Simple organic molecules form complex materials through self-organisation
An international team of researchers lead by the Technical University of Munich (TUM) has discovered a reaction path that produces exotic layers with semiregular structures. These kinds of materials are interesting because they frequently possess extraordinary properties. In the process, simple organic molecules are converted to larger units which form the complex, semiregular patterns. With experiments at BESSY II at Helmholtz-Zentrum Berlin this could be observed in detail.
Only a few basic geometric shapes lend themselves to covering a surface without overlaps or gaps using uniformly shaped tiles: triangles, rectangles and hexagons. Considerably more and significantly more complex regular patterns are possible with two or more tile shapes. These are so-called Archimedean tessellations or tilings.
Materials can also exhibit tiling characteristics. These structures are often associated with very special properties, for example unusual electrical conductivity, special light reflectivity or extreme mechanical strength. But, producing such materials is difficult. It requires large molecular building blocks that are not compatible with traditional manufacturing processes.
Image: The new building block (left, red outline) comprises two modified starting molecules connected to each other by a silver atom (blue). This leads to complex, semiregular tessellations (right, microscope image).
Credit: Klappenberger and Zhang / TUM