New SLAC-Stanford Battery Center targets roadblocks to a sustainable energy transition

The center at SLAC aims to bridge the gaps between discovering, manufacturing and deploying innovative energy storage solutions. 

The Department of Energy’s SLAC National Accelerator Laboratory and Stanford University today announced the launch of a new joint battery center at SLAC. It will bring together the resources and expertise of the national lab, the university and Silicon Valley to accelerate the deployment of batteries and other energy storage solutions as part of the energy transition that’s essential for addressing climate change.

A key part of this transition will be to decarbonize the world’s transportation systems and electric grids ­– to power them without fossil fuels. To do so, society will need to develop the capacity to store several hundred terawatt-hours of sustainably generated energy. Only about 1% of that capacity is in place today.

Filling the enormous gap between what we have and what we need is one of the biggest challenges in energy research and development. It will require that experts in chemistry, materials science, engineering and a host of other fields join forces to make batteries safer, more efficient and less costly and manufacture them more sustainably from earth-abundant materials, all on a global scale. 

The SLAC-Stanford Battery Center will address that challenge. It will serve as the nexus for battery research at the lab and the university, bringing together large numbers of faculty, staff scientists, students and postdoctoral researchers from SLAC and Stanford for research, education and workforce training. 

 “We’re excited to launch this center and to work with our partners on tackling one of today’s most pressing global issues,” said interim SLAC Director Stephen Streiffer. “The center will leverage the combined strengths of Stanford and SLAC, including experts and industry partners from a wide variety of disciplines, and provide access to the lab’s world-class scientific facilities. All of these are important to move novel energy storage technologies out of the lab and into widespread use.”

Expert research with unique tools

Research and development at the center will span a vast range of systems – from understanding chemical reactions that store energy in electrodes to designing battery materials at the nanoscale, making and testing devices, improving manufacturing processes and finding ways to scale up those processes so they can become part of everyday life. 

“It’s not enough to make a game-changing battery material in small amounts,” said Jagjit Nanda, a SLAC distinguished scientist, Stanford adjunct professor and executive director of the new center, whose background includes decades of battery research at DOE’s Oak Ridge National Laboratory. “We have to understand the manufacturing science needed to make it in larger quantities on a massive scale without compromising on performance.”

Longstanding collaborations between SLAC and Stanford researchers have already produced many important insights into how batteries work and how to make them smaller, lighter, safer and more powerful. These studies have used machine learning to quickly identify the most promising battery materials from hundreds made in the lab, and measured the properties of those materials and the nanoscale details of battery operation at the lab’s synchrotron X-ray facility. SLAC’s X-ray free-electron laser is available, as well, for fundamental studies of energy-related materials and processes. 

SLAC and Stanford also pioneered the use of cryogenic electron microscopy (cryo-EM), a technique developed to image biology in atomic detail, to get the first clear look at finger-like growths that can degrade lithium-ion batteries and set them on fire. This technique has also been used to probe squishy layers that build up on electrodes and must be carefully managed, in research performed at the Stanford Institute for Materials and Energy Sciences (SIMES).

Nanda said the center will also focus on making energy storage more sustainable, for instance by choosing materials that are abundant, easy to recycle and can be extracted in a way that’s less costly and produces fewer emissions.

Read more on the SLAC website

Researchers identify new material for creating electronic devices

A multidisciplinary research team is developing more efficient and environmentally friendly processes to build light-emitting diodes with the help of the Canadian Light Source (CLS) at the University of Saskatchewan.

Dr. Simon Trudel, professor in chemistry at the University of Calgary and director of the university’s Nanoscience Program, said his team has been studying ways to use amorphous materials to build better “optoelectronic devices” such as organic photovoltaic cells or organic light-emitting diodes (OLEDs), which make possible digital display TV screens, computer monitors and smartphones.

By using a technique called X-ray Absorption Spectroscopy (XAS) at the CLS, Trudel’s team was able to precisely examine the structure of the materials they were experimenting with to create more efficient electronic cells.

Trudel’s team focused on one of the interior layers of the diode called the hole-transport layer, which regulates the movement of electrons — and electrical energy — in a device. They identified an amorphous vanadium oxide compound that could be used for the hole-transfer layer but did not require the standard-but-intense heat treatments to crystallize the material.

Read more on the Canadian Light Source website

Image: Digital displays

#SynchroLightAt75 – Rod MacKinnon’s Nobel Prize in chemistry

Rod MacKinnon – Nobel Prize in chemistry 2003 for work on the structure of ion channels  

The structural work of MacKinnon was carried out primarily at the Cornell High Energy Synchrotron Source (CHESS) and the National Synchrotron Light Source (NSLS) at Brookhaven. At the time, CHESS was a first-generation SR source.  The award for MacKinnon’s work was the second recognition of SR work by the Nobel Committee. MacKinnon acknowledges the crucial role that the two synchrotron facilities, Cornell Synchrotron (CHESS/MacCHESS) and NSLS, have played in his research on the protein crystallography of membrane channels.

He said, `Without exaggeration that most of what is known about the chemistry and structure of ion channels has come from experiments carried out at these SR centres’.

Rod MacKinnon

Read more on the Nobel Prize website

Image: View showing the location of CHESS, which is underground at Cornell

Credit: Jon Reis

ESRF appoints two new Directors of Research

Gema Martínez-Criado and Annalisa Pastore have been appointed new ESRF directors of research. Martínez-Criado will cover Condensed Matter and Physical and Material Sciences and Pastore Life Sciences, Chemistry and Soft Matter Science.

In its statement, the ESRF Council « unanimously approved the appointments, for a five-year period starting on 01 January 2022, of Dr Gema Martínez Criado, from the Spanish Research Council’s Materials Science Institute of Madrid, as Director of Research for Condensed Matter and Physical and Material Sciences, and of Professor Annalisa Pastore, from King’s College London University, as Director of Research for Life Sciences, Chemistry and Soft Matter Science. » The ESRF Council also « acknowledged the fact that both of these positions were being filled by female candidates of high calibre and expressed the full trust of the Council to continue to lead, in the coming year, the efforts required to fully capitalise on the world leading performances of the EBS storage ring and suite of beamlines.”

Read more on the ESRF website

Image: Gema Martínez-Criado (left) and Annalisa Pastore (right) have been appointed new ESRF directors of research

Credit: ESRF

Unusual reversibility of molecular break-up of PAHs

By combining the high-resolution x-ray photoelectron spectroscopy at the SuperESCA beamline of Elettra with density functional theory a group of scientists from Italy, UK, Denmark and Germany has shown that the process of hydrogen removal from pentacene molecules adsorbed on Ir(111) follows a reversible chemical route, which allows hydrogen re-attachment to the carbon nanoribbon formed after the thermally induced C–H bond break-up. The thermal dissociation taking place upon controlled annealing can be reversed by cooling the system at room temperature and in a hydrogen atmosphere.


Besides the novelty of the chemical process, this phenomenon could have interesting implications for molecular electronics and for the manipulation of graphene nanoribbons which are known to present higher electron/hole mobilities and better thermal transport when dehydrogenated. 

Read more on the Elettra website

Producing less costly, greener hydrogen peroxide

Australian researchers led by the University of New South Wales have used the Australian Synchrotron to understand how the chemical structure of an advanced catalytic material contributes to its stability and efficiency. The approach has the potential to produce hydrogen peroxide (H2O2) in a process that is cost-effective with less harm to the environment.

Hydrogen peroxide is an important chemical that used widely in a range of applications, including wastewater treatment, disinfection, paper/pulp bleaching, semi-conductor cleaning, mining and metal processing, fuel cells and in chemical synthesis.

According to an international market research group, IMARC, the global hydrogen peroxide market size was valued at US$4.0 billion in 2017 and is increasing.

Read more on the ANSTO website

Image: The optimized geometry structures of bare CoN4 moiety and CoN4 moieties with different coverages of epoxy oxygen. The gray, blue, orange and red balls represent C, N, Co and O atoms, respectively [Reprinted with permission by Creative Commons License: Attribution 4.0 International (CC BY 4.0)]

Milling towards Green Chemistry

Real-time X-ray investigations reveal strong influence of milling equipment on mechanochemical reactions

The result of mechanochemical synthesis can be altered simply by selecting different milling jars and balls. Using the bright X-ray light from PETRA III (shown in green), the team was able to follow the formation of different polymorphs live. (Credit: McGill University, Luzia Germann)

The physical properties of milling jars and balls used in mechanically driven chemical reactions have a considerable influence on the reaction mechanism and outcome. Achieved at PETRA III, this is the result of a time-resolved X-ray study of mechanochemical syntheses. It shows that the material of milling jars, as well as the size and material of the milling balls can be specifically used to control the results of mechanochemical co-crystallisations, as Luzia S. Germann from McGill University (Canada) and co-workers report in the Royal Society of Chemistry’s journal Chemical Science.

Mechanochemistry has recently gained a lot of attention as a cornerstone of green and environmentally-friendly solvent-free synthetic methods. The results of the synchrotron X-ray powder diffraction experiments will contribute to a better understanding of mechanochemical processes and how they can be used in the future to explore the synthesis of new materials.

Read more on the DESY website

Image: The result of mechanochemical synthesis can be altered simply by selecting different milling jars and balls. Using the bright X-ray light from PETRA III (shown in green), the team was able to follow the formation of different polymorphs live. (Credit: McGill University, Luzia Germann)

First direct look at how light excites electrons to kick off a chemical reaction

Light-driven reactions are at the heart of human vision, photosynthesis and solar power generation. Seeing the very first step opens the door to observing chemical bonds forming and breaking.

The first step in many light-driven chemical reactions, like the ones that power photosynthesis and human vision, is a shift in the arrangement of a molecule’s electrons as they absorb the light’s energy. This subtle rearrangement paves the way for everything that follows and determines how the reaction proceeds.
Now scientists have seen this first step directly for the first time, observing how the molecule’s electron cloud balloons out before any of the atomic nuclei in the molecule respond.

While this response has been predicted theoretically and detected indirectly, this is the first time it’s been directly imaged with X-rays in a process known as molecular movie-making, whose ultimate goal is to observe how both electrons and nuclei act in real time when chemical bonds form or break.

>Read more on the LCLS at SLAC website

Image: extract, full image here

Researchers use CHESS to map protein motion

Cornell structural biologists took a new approach to using a classic method of X-ray analysis to capture something the conventional method had never accounted for: the collective motion of proteins.

And they did so by creating software to painstakingly stitch together the scraps of data that are usually disregarded in the process.
Cornell structural biologists took a new approach to using a classic method of X-ray analysis to capture something the conventional method had never accounted for: the collective motion of proteins. And they did so by creating software to painstakingly stitch together the scraps of data that are usually disregarded in the process.
Their paper, “Diffuse X-ray Scattering from Correlated Motions in a Protein Crystal,”published March 9 in Nature Communications.
As a structural biologist, Nozomi Ando, M.S. ’04, Ph.D. ’08, assistant professor of chemistry and chemical biology, is interested in charting the motion of proteins, and their internal parts, to better understand protein function. This type of movement is well known but has been difficult to document because the standard technique for imaging proteins is X-ray crystallography, which produces essentially static snapshots.

>Read more on the CHESS website
>Read also: Diffuse X-ray Scattering from Correlated Motions in a Protein Crystal

Image: This slice through the three-dimensional diffuse map shows intense peaks resulting from lattice vibration, as well as cloudy features caused by internal protein motions.

Shaping attosecond waveforms

Scientists show how to control attosecond light pulses at a free-electron laser.

Chemical reactions and complex phenomena in liquids and solids are determined by the movement and rearrangement of electrons. These movements, however, occur on an extremely short timescale, typically only a few hundred attoseconds (1 attosecond =10-18 s or one quintillionth of a second).  Only light pulses of a comparable duration can be used to take snapshots of the dynamics of electrons. An international team of researchers led by Guiseppe Sansone from the University of Freiburg and including scientists from European XFEL have now, for the first time, been able to reliably generate, control and characterize such attosecond light pulses from a free-electron laser.

“These pulses enable us to study the first moment of the electronic response in a molecule or crystal,” explains Sansone. “With the ability to shape the electric field enables us to control electronic movements – with the long-term goal of optimising basic processes such as photosynthesis or charge separation in materials.”

>Read more on the European XFEL website

Image: Scientists have been able to shape the electric field of an attosecond light pulse.
Credit: Jürgen Oschwald and Carlo Callegari

Inventing a way to see attosecond electron motions with an X-ray laser

Called XLEAP, the new method will provide sharp views of electrons in chemical processes that take place in billionths of a billionth of a second and drive crucial aspects of life.

Researchers at the Department of Energy’s SLAC National Accelerator Laboratory have invented a way to observe the movements of electrons with powerful X-ray laser bursts just 280 attoseconds, or billionths of a billionth of a second, long.

The technology, called X-ray laser-enhanced attosecond pulse generation (XLEAP), is a big advance that scientists have been working toward for years, and it paves the way for breakthrough studies of how electrons speeding around molecules initiate crucial processes in biology, chemistry, materials science and more.
The team presented their method today in an article in Nature Photonics.

“Until now, we could precisely observe the motions of atomic nuclei, but the much faster electron motions that actually drive chemical reactions were blurred out,” said SLAC scientist James Cryan, one of the paper’s lead authors and an investigator with the Stanford PULSE Institute, a joint institute of SLAC and Stanford University. “With this advance, we’ll be able to use an X-ray laser to see how electrons move around and how that sets the stage for the chemistry that follows. It pushes the frontiers of ultrafast science.”

Image: A SLAC-led team has invented a method, called XLEAP, that generates powerful low-energy X-ray laser pulses that are only 280 attoseconds, or billionths of a billionth of a second, long and that can reveal for the first time the fastest motions of electrons that drive chemistry. This illustration shows how the scientists use a series of magnets to transform an electron bunch (blue shape at left) at SLAC’s Linac Coherent Light Source into a narrow current spike (blue shape at right), which then produces a very intense attosecond X-ray flash (yellow).
Credit: Greg Stewart/SLAC National Accelerator Laboratory

>Read more on the Linear Coherent Light Source (SLAC) website

A new stable form of plutonium discovered

An international team of scientists, led by the Helmholtz Zentrum Dresden-Rossendorf (HZDR), have found a new compound of plutonium with an unexpected, pentavalent oxidation state.

This new phase of plutonium is solid and stable, and may be a transient phase in radioactive waste repositories. The results are published this week in Angewandte Chemie as a Very Important Paper (VIP). Countries across the globe are making efforts to improve the safety of the nuclear waste storage in order to prevent release of radioactive nuclides to the environment. Plutonium, has been shown to be transported by groundwaters from contaminated sites for kilometres in the form of colloids, which are formed by interaction with clay, iron oxides or natural organic matter. 
A team of scientists lead by  HZDR studies the chemistry of actinides under environmentally relevant conditions, by synthesizing such compounds, and then studying their electronic and structural behaviour both with advanced synchrotron X-ray methods experimentally as well as theoretically. The latest paper of the international team shows how an experiment seemingly gone wrong leads to a breakthrough: the discovery of a new stable form of plutonium.
It all started when Kristina Kvashnina, physicist from HZDR and based at the ROBL beamline at the ESRF, and her team were trying to create plutonium dioxide nanoparticles using different precursors to be studied at ROBL. When they used the Pu (VI) precursor, they realized that a strange reaction took place during the formation of the plutonium dioxide nanoparticles. “Every time we create nanoparticles from the other precursors Pu(III), (IV) or (V) the reaction is very quick, but here we observed a weird phenomenon half way”, explains Kvashnina. She figured that it must be Pu (V), pentavalent plutonium, a never-observed-before form of the element, after doing a high-energy resolution fluorescence detection (HERFD) experiment at the Pu L3 edge at ROBL.

>Read more about the research at ROBL on the ESRF website

Image: The team in front of the spectrometer of ROBL. Kristina Kvashnina is the second from the right.

Worldwide scientific collaboration develops catalysis breakthrough

A new article  just published in Nature Catalysis shows the simple ways of controlling the structure of platinum nanoparticles and tuning their catalytic properties. 

Research led by Cardiff Catalysis Institute (CCI) in collaboration with scientists from Lehigh University, Jazan University, Zhejiang University, Glasgow University, University of Bologna, Research Complex at Harwell (RCaH), and University College London have combined their unique skills to develop and understand using advanced characterisation methods (particularly TEM and B18 at Diamond Light Source), how it is possible to use a simple preparation method to control and manipulate the structures of metal nanoparticles. These metal nanoparticles are widely used by industry as innovative catalysts for the production of bulk chemicals like polymers, liquid fuels (e.g., diesel, petrol) and other speciality chemicals (pharmaceutical products).

>Read more on the Diamond Light Source website

Image: Andy Beale works at Diamond Light Source.

Analysis of fingermarks with synchrotron techniques provide new insights

A new study by researchers from Curtin University using the infrared (IR) and X-ray fluorescence microscopy (XFM) beamlines at the Australian Synchrotron has provided a better understanding of the chemical and elemental composition of latent fingermarks.

The findings by lead researchers Prof Simon Lewis and Dr Mark Hackett may provide opportunities to optimise current fingermark detection methods or identify new detection strategies for forensic purposes.
Latent fingermarks are generally described as those requiring some process to make them readily visible to the eye. These fingermarks are typically made up of natural skin secretions, along with contaminants (such as food or cosmetics) picked up from various surfaces.
The detection of latent fingermarks is often crucial in forensic investigations, but this is not always a straightforward task. “We know that there are issues in detecting fingermarks as they get older, and also under certain environmental conditions”, said Lewis, whose main research focus is forensic exchange evidence.

“In order to improve our ability to detect fingermarks, we need to understand the nature of fingermark residue, and this includes both the organic and inorganic components. Many chemical components in fingermark residue are present at very low levels, and we don’t know how they are distributed within the fingermark. This is what took us to the Australian Synchrotron.”

>Read more on the Australian Synchrotron at ANSTO website

Study reveals ‘radical’ wrinkle in forming complex carbon molecules in space

Unique experiments at Berkeley Lab’s Advanced Light Source shine a light on a new pathway for carbon chemistry to evolve in space.

A team of scientists has discovered a new possible pathway toward forming carbon structures in space using a specialized chemical exploration technique at the Department of Energy’s Lawrence Berkeley National Laboratory (Berkeley Lab). The team’s research has now identified several avenues by which ringed molecules known as polycyclic aromatic hydrocarbons, or PAHs, can form in space. The latest study is a part of an ongoing effort to retrace the chemical steps leading to the formation of complex carbon-containing molecules in deep space. PAHs – which also occur on Earth in emissions and soot from the combustion of fossil fuels – could provide clues to the formation of life’s chemistry in space as precursors to interstellar nanoparticles. They are estimated to account for about 20 percent of all carbon in our galaxy, and they have the chemical building blocks needed to form 2D and 3D carbon structures.

>Read more on the ALS at Berkeley Lab website

Image: This composite image shows an illustration of a carbon-rich red giant star (middle) warming an exoplanet (bottom left) and an overlay of a newly found chemical pathway that could enable complex carbons to form near these stars.
Credits: ESO/L. Calçada; Berkeley Lab, Florida International University, and University of Hawaii at Manoa.

Brookhaven Lab and University of Delaware begin joint initiative

Through this partnership, scientists from both institutions will conduct collaborative research on rice soil chemistry and quantum materials.

The U.S. Department of Energy’s (DOE) Brookhaven National Laboratory and the University of Delaware (UD) have begun a two-year joint initiative to promote collaborative research in new areas of complementary strength and strategic importance. Though Brookhaven Lab and UD already have a tradition of collaboration, especially in catalysis, this initiative encourages partnerships in strategic areas where that tradition does not yet exist. After considering several potential areas, a committee from Brookhaven and UD selected two projects—one on rice soil chemistry and the other on quantum materials—for the new initiative. For each project, one graduate student based at Brookhaven and one graduate student from UD will work with and be supervised by a principal investigator from each respective institution. The research, to start in October 2019, is funded separately by the two institutions. Brookhaven funding is provided through its Laboratory-Directed Research and Development program, which promotes highly innovative and exploratory research that supports the Lab’s mission and areas for growth.

>Read more on the NSLS-II at Brookhaven Lab website

Image: Principal investigators from Brookhaven Lab and the University of Delaware (UD) will collaborate on two different research projects through a new joint initiative. Brookhaven’s Peter Johnson (left) and UD’s Stephanie Law (second from left) will measure the energy level spectrum of a topological insulator, a new type of material that behaves as an insulator internally but as a conductor on the surface; Brookhaven’s Ryan Tappero (second from the right) and UD’s Angelia Seyfferth (right) will study how toxic and nutrient metals are distributed in rice grain.