A new way to control the magnetic properties of rare earth elements

The special properties of rare earth magnetic materials are due to the electrons in the 4f shell. Until now, the magnetic properties of 4f electrons were considered almost impossible to control. Now, a team from HZB, Freie Universität Berlin and other institutions has shown for the first time that laser pulses can influence 4f electrons- and thus change their magnetic properties. The discovery, which was made through experiments at EuXFEL and FLASH, opens up a new way to data storage with rare earth elements.

The strongest magnets we know of are based on rare earths. Their 4f electrons are responsible for their magnetic properties: they generate a large magnetic moment that is maintained even when their chemical environment changes. This means that rare earths can be used in very different compounds and alloys without changing their special magnetic properties. Until now, it was assumed that the magnetic properties of 4f electrons could not be changed even if the material was excited with a laser pulse. But indeed, this is possible, as a team from HZB, Freie Universität Berlin, DESY, the European X-ray laser XFEL and other institutions has now shown: The spatial arrangement of the 4f electrons can be briefly switched by laser excitation. This also changes their magnetism. This effect opens up new possibilities for the fast and energy-efficient control of magnetic rare-earth materials. The work has now been published in the journal Science Advances.

Read more on HZB website

Image: The image shows the terbium orbitals between which the excitation takes placeand a schematic sketch of the excitation process. 

Credit: HZB

Unveiling finer details in the physics of materials

Scientists at the European XFEL’s SCS instrument routinely use a technique called transient X-ray absorption spectroscopy (XAS) to investigate materials that have applications in data storage and processing, catalysis, or in the search for room temperature superconductors. Investigating very small changes in the motion of electrons within a material’s structure on ultrashort timescales provides scientists with fingerprints of the complex processes at play within them. This helps them characterise samples that are important for energy and materials research.

Using the European XFEL’s brilliant pulses, researchers can overcome some of the issues of conventional transient XAS—such as long measurement times—but the varying intensity of European XFEL’s pulses provides its own challenges. Now, scientists at SCS have implemented a new sampling scheme for improving the efficiency of such measurements.

Read more on the European XFEL website

Image: The X-ray beam is split into three copies. Two of these copies are passed through identical samples of the material under investigation, with one of these samples also being illuminated by a laser (‘optical laser’ in the figure). This transforms it into a new state, interesting to researchers. From this, scientists are able to ‘subtract’ detrimental noise, revealing the finest details of the sample under investigation.