Pigments in Oil Paintings Linked to Artwork Degradation

Scientists have observed how lithium moves inside individual nanoparticles that make up batteries.

The finding could help companies develop batteries that charge faster and last longer. Experts have long known that as oil paintings age, soaps can form within the paint, degrading the appearance of the artworks. The process significantly complicates the preservation of oil paintings—and cultural manifestations, which the paintings themselves help to preserve.

“These soaps may form protrusions that grow within the paint and break up through the surface, creating a bumpy texture,” said Silvia Centeno, a member of the Department of Scientific Research at the New York Metropolitan Museum of Art (The Met). “In other cases, the soaps can increase the transparency of the paint, or form a disfiguring, white crust on the painting.”

Scientists do not understand why the soaps take on different manifestations, and for many years, the underlying mechanisms of how the soaps form remained a mystery.

“The Met, alongside our colleagues from other institutions, is trying to figure out why the process takes place, what triggers it, and if there’s a way we can prevent it,” Centeno said.

 

>Read more on the NSLS-II website

Picture: Scientists from Brookhaven Lab and The Met used beamline 5-ID at NSLS-II to analyze a microscopic sample of a 15th century oil painting. Pictured from left to right are Karen Chen-Wiegart (Stony Brook University/BNL), Silvia Centeno (The Met), Juergen Thieme (BNL), and Garth Williams (BNL).