In situ spectroscopy as a probe of electrocatalyst performance

Hydrogen fuel cells generally require expensive and scarce platinum catalysts in order to function. Researchers have created highly reactive platinum-nickel nanowires with the potential to reduce the amount of platinum required in fuel cells. Research at PIPOXS examines the atomic-level mechanisms of this catalyst, forming a foundation for the development and commercialization of more efficient fuel cell technology.

What is the new discovery?

The oxygen reduction reaction (ORR) is an important and often limiting component of hydrogen fuel cell operation.  To facilitate this reaction, platinum-based catalysts are often used to increase its rate, though the expense and limited availability of Pt present challenges to its widespread use.  In this work, researchers selectively replaced a portion of the nickel atoms of nickel nanowires with platinum to create platinum-nickel nanowires (PtNi-NWs) as high surface area catalysts that reduced the total amount of platinum required.  These PtNi-NWs were found to be highly active, and so operando x-ray absorption spectroscopy and extended x-ray absorption fine structure (EXAFS) experiments were conducted at the PIPOXS beamline to assess the electronic and geometric changes occurring in these catalysts during their use.   These data enabled the researchers to determine that the Pt formed an alloy with the Ni in the NW and that its interaction with oxygen remained constant regardless of the external potential applied.  

Read more on the CHESS website

Image: Schematic showing the electrochemical cell used for the operando measurements, and how the EXAFS data can be used to deduce the chemistry happening during this reaction.