Plant leaves inspire design of improved fuel cell

Hydrogen fuel cells convert hydrogen and oxygen into electricity, heat, and water. Because this conversion process doesn’t generate any carbon emissions, fuel cells are seen as a valuable source of green energy that could be key in addressing climate change.

However, there’s an obstacle standing in the way of their use in large-scale applications – powering electric trucks for long-haul transport, for example, or replacing diesel generators to provide electricity in remote, northern communities. Current fuel cells have reached a ceiling in the amount of electricity they can generate because their internal structure cannot adequately manage all of the water that cells create as a byproduct.

Researchers from the University of Toronto’s Department of Mechanical and Industrial Engineering looked to a novel source when they were brainstorming for ideas to improve the design of the channels — called “flow fields” — that direct water inside the cell. PhD student Eric Chadwick says that, instead of starting from scratch, he turned to nature for inspiration (“biomimicry”). “Rather than trying to come up with a brand-new design, I decided to look toward nature, as often some organism has already, through evolution, optimized a process.”

In this case, the process was moving water in a single direction. He found evidence of this on the skin of lizards and the leaves of certain plants. “Lizards living in dry, arid climates have scales that have evolved to trap condensation from air and channel it to their eyes and mouth,” says Chadwick. “Similarly, on certain types of leaves the veins catch water and move it to tips of the leaves so that it falls down, so the roots can absorb it.” He and his team incorporated these patterns from nature into the channels within their new cell, to more effectively move water from the porous layer inside the cell to the outside of the cell.

Using the Canadian Light Source at the University of Saskatchewan, Chadwick and his colleagues found the nature-inspired design resulted in a 30% increase in the peak power density they could reach in the fuel cell, compared to existing designs. The new cell design showed a more even distribution of water within the cell, with no build up, which also meant more even distribution of the reactants (oxygen and hydrogen) – “so the fuel cell is using the catalyst (platinum) more effectively.” The researchers also found that, because the new design removed excess liquid water from the porous layer, the channels served as additional pathways for more reactant to get to the catalyst layer.

With the high-energy X-rays at the CLS, Chadwick and the team were able to generate richly detailed, cross-sectional images of their new fuel cell while it was operating. “We were able see exactly where the water is going, how much is remaining in the cell, with the different designs we tested,” says Chadwick. In the old design, we used to have this heterogeneous distribution of water. Now we have a much more homogeneous layer of water, which in turn means we have a much more homogenous distribution of the reactants and we’re using the catalyst in the fuel cell much more effectively and evenly.”

Read more on CLS website

Image: Plant leaves inspire design of improved fuel cell

In situ spectroscopy as a probe of electrocatalyst performance

Hydrogen fuel cells generally require expensive and scarce platinum catalysts in order to function. Researchers have created highly reactive platinum-nickel nanowires with the potential to reduce the amount of platinum required in fuel cells. Research at PIPOXS examines the atomic-level mechanisms of this catalyst, forming a foundation for the development and commercialization of more efficient fuel cell technology.

What is the new discovery?


The oxygen reduction reaction (ORR) is an important and often limiting component of hydrogen fuel cell operation.  To facilitate this reaction, platinum-based catalysts are often used to increase its rate, though the expense and limited availability of Pt present challenges to its widespread use.  In this work, researchers selectively replaced a portion of the nickel atoms of nickel nanowires with platinum to create platinum-nickel nanowires (PtNi-NWs) as high surface area catalysts that reduced the total amount of platinum required.  These PtNi-NWs were found to be highly active, and so operando x-ray absorption spectroscopy and extended x-ray absorption fine structure (EXAFS) experiments were conducted at the PIPOXS beamline to assess the electronic and geometric changes occurring in these catalysts during their use.   These data enabled the researchers to determine that the Pt formed an alloy with the Ni in the NW and that its interaction with oxygen remained constant regardless of the external potential applied.  

Read more on the CHESS website

Image: Schematic showing the electrochemical cell used for the operando measurements, and how the EXAFS data can be used to deduce the chemistry happening during this reaction.

A 1-Atom-Deep Look at a Water-Splitting Catalyst

X-ray experiments at the U.S. Department of Energy’s Lawrence Berkeley National Laboratory (Berkeley Lab) revealed an unexpected transformation in a single atomic layer of a material that contributed to a doubling in the speed of a chemical reaction – the splitting of water into hydrogen and oxygen gases. This process is a first step in producing hydrogen fuel for applications such as electric vehicles powered by hydrogen fuel cells.

The research team, led by scientists at SLAC National Accelerator Laboratory, performed a unique X-ray technique and related analyses, pioneered at Berkeley Lab’s Advanced Light Source (ALS), to home in on the changes at the surface layer of the material. The ALS produces X-rays and other forms of intense light to carry out simultaneous experiments at dozens of beamlines.

Read more on the LBL website

Image: This illustration shows two possible types of surface layers for a catalyst that performs the water-splitting reaction, the first step in making hydrogen fuel: The gray surface is lanthanum oxide and the colorful surface is nickel oxide. A rearrangement of nickel oxide’s atoms while carrying out the reaction made it twice as efficient. Researchers hope to harness this phenomenon to make better catalysts. Lanthanum atoms are depicted in green, nickel atoms in blue, and oxygen atoms in red.

Credit: CUBE3D