Improving steel pipelines for safe transport of hydrogen

USask researchers use synchrotron light to capture 3D images of cracks that form inside steel.

Hydrogen is increasingly gaining attention as a promising energy source for a cleaner, more sustainable future. Using hydrogen to meet the energy demands for large-scale applications such as utility infrastructure will require transporting large volumes via existing pipelines designed for natural gas.

But there’s a catch. Hydrogen can weaken the steel that these pipelines are made of. When hydrogen atoms enter the steel, they diffuse into its microstructure and can cause the metal to become brittle, making it more susceptible to cracking. Hydrogen can be introduced into the steel during manufacturing, or while the pipeline is in service transporting oil and gas.

To better understand this problem, researcher Tonye Jack used the Canadian Light Source (CLS) at the University of Saskatchewan (USask) to capture a 3D view of the cracks formed in steels. Researchers have previously relied on two-dimensional imaging techniques, which don’t provide the same rich detail made possible with synchrotron radiation.

Tonye, a PhD candidate in USask’s Department of Mechanical Engineering, and his colleagues studied different pipeline steels and showed that microstructure plays a critical role in how much hydrogen the steel absorbs and how it is distributed in the metal. Their research also revealed that when hydrogen enters the steel while the pipeline is in service, it causes more damage than if introduced during manufacturing or other pre-charging conditions.

The risk of steel failure due to hydrogen embrittlement depends on several factors such as the amount of hydrogen in the steel, the steel’s microstructure, stress conditions, and operating environment. However, Tonye emphasizes that how much hydrogen is retained in the steel and where it accumulates largely dictates its failure behavior.

“We need to know the mechanism of failure and how to mitigate it,” he says.

While catastrophic pipeline failures are rare, his team’s findings are important as industries plan to transport hydrogen gas using high-strength natural gas pipelines. “These findings can help inform the production of safer pipelines,” he says. By refining the microstructure, manufacturers can design steels that are more resistant to cracking and hydrogen embrittlement.

Read more on CLS website

Understanding Stainless Steel’s Resistance to Hydrogen Embrittlement

Stainless steel is one of our most versatile materials. Its hygienic qualities ensure the safety of medical instruments and implants, and its corrosion-resistant properties make it indispensable in industries from construction to food processing. The corrosion resistance arises from the alloy’s chromium content, as the chromium forms a passive film on the surface that can self-heal in the presence of oxygen, shielding the bulk of the material from corrosion. However, the stability of the passive film can be affected by hydrogen absorption, leading to microstructure embrittlement that lowers the stress required for cracks to occur and propagate in the metal. A challenge for the hydrogen energy industry is that high-performance metallic materials are highly susceptible to hydrogen embrittlement. One potential candidate for building a safe hydrogen economy infrastructure is super duplex stainless steel (SDSS). 

In work recently published in Applied Surface Science, an international team of researchers used in situ surface-sensitive synchrotron X-ray measurements to investigate the early stages of hydrogen-induced degradation of SDSS occurring at the near surface. Their results show that SDSS’s exceptional resistance to hydrogen embrittlement can be explained by the stability of the passive oxide film, and that the semiconducting property of the passive film plays an important role in hydrogen embrittlement. The authors also conclude that profound in situ experimental characterisation and computational calculation are needed to reveal the complex processes behind material degradation. 

High-Strength, Corrosion-Resistant Steel

Green hydrogen can be used as both a feedstock and energy carrier and has the potential to play a crucial role in the future fossil-free energy landscape. However, high-strength metallic materials are highly susceptible to hydrogen embrittlement (hydrogen-induced material degradation), posing a significant challenge for safe hydrogen storage and transport.

Prof Jinshan Pan, from the KTH Royal Institute of Technology in Sweden, said:

Hydrogen embrittlement is a very important issue for many applications. Different metal materials may have this embrittlement problem. It’s really a hundred-years-old challenge. In many cases, the metal surface has a passive film, like an oxide, that allows materials to be used in practice, because otherwise the metals themselves are active.

Read more on Diamond website