Fighting food waste: Reducing grain spoilage in storage could help feed growing global population

Dr. Digvir Jayas is on a mission to stop grain spoilage. The researcher has been helping farmers and grain managers reduce spoilage losses for 40 years. He recently published a new study that used the Canadian Light Source at the University Saskatchewan to peer inside grains themselves, looking for the signs of spoilage and resistance.

Spoiled grain represents a huge pool of potential food that could help feed a growing global population. Spoilage rates vary greatly between grains and storage conditions, from as low as 1% of stored grain lost up to 50%.

“So, if you took an average of 20% loss, that would mean 640 million tonnes of grain is being lost globally on an annual basis,” says Jayas, who conducted the research while he was in the Department of Biosystems Engineering (Price Faculty of Engineering) at the University of Manitoba. “We could feed 1.5 billion people by preventing that loss through spoilage.”

To understand how the grain itself can be bred, and specific varieties selected to maximize storage potential, his team focused on hard durum wheat, which spoils less easily than soft wheats.

“The CLS has such a unique capability to look at the composition of materials at a nano or micro level. When grain spoils, there are unique changes occurring in the grain, and we were able to look at those changes.”

Read more on Canadian Light Source website

X-rays look at nuclear fuel cladding with new detail

Micro-beam measurements at the Swiss Light Source SLS have enabled insights into the crystal structure of hydrides that promote cracks in nuclear fuel cladding. This fundamental knowledge of the material properties of cladding will help assess safety during storage.

For over seventy years, zirconium alloys have been used as cladding for nuclear fuel rods. This cladding provides a structural support for the nuclear fuel pellets and an initial barrier to stop fission products escaping into the reactor water during operation. During its long history, which includes extensive research and development advances, reactor type zirconium alloys have proved themselves as an extremely successful material for this application.

Yet they have a well-known nemesis: hydrogen. When submerged in water during operation in a reactor, at the hot surface of the fuel rod water molecules split into hydrogen and oxygen. Some of this hydrogen then diffuses into the cladding. It makes its way through the cladding until – when the concentration and conditions are right – it precipitates to form chemical compounds known as zirconium-hydrides. These hydrides make the material brittle and prone to cracking. Now, using the Swiss Light Source SLS, researchers were able to shed new light on the interplay between cracking and hydride formation.

Using a technique called synchrotron micro-beam X-ray diffraction, the researchers could study the structure of hydrides during the growth of cracks in fuel cladding at a new level of detail. “Through thermomechanical tests, we could control extremely slow crack propagations. Discovering at such high spatial resolution which hydride formations actually occurred made all the challenges of the material preparation worthwhile,” says study first author, Aaron Colldeweih who designed the thermomechanical testing procedure as part of his PhD project at PSI.

One of the things they discovered was that an unexpected type of hydride was present at the crack tip. This type of hydride, known as gamma-hydride has a slightly different crystal structure and stoichiometry to the type more commonly present, known as delta-hydride, “There has been a lot of discussion about gamma-hydrides: whether they are stable and whether they exist at all. Here we could show that with certain applied stresses you create gamma-hydrides that are stable,” says Johannes Bertsch, who leads the Nuclear Fuels Group in the Laboratory of Nuclear Materials at PSI.

Read more on the PSI website

Image: Malgorzata Makowska, scientist at the MicroXAS beamline of the SLS, carefully positions a standard material for setup calibration on the sample manipulator in front of the X-ray beam.

Credit: Paul Scherrer Institute / Mahir Dzambegovic