The research team working under the leadership of Prof. Anna Zielińska-Jurek from the Faculty of Chemistry at Gdańsk University of Technology, in cooperation with scientists from ASTRA beamline, developed and characterized a new semiconductor material based on bismuth orthovanadate (BiVO4) and copper oxide sub-nanoclusters (CuOx). This material, when exposed to visible light, is able to effectively remove pharmaceuticals in water. Measurements made at the SOLARIS synchrotron using X-ray absorption spectroscopy (XAS) revealed the oxidation state of copper oxides. The research results were published in the journal “Separation and Purification Technology” from Elsevier publisher.
The rapid development of medicine and the pharmaceutical industry has made pharmaceutical pollution one of the greatest environmental dangers. Some of the most frequently detected pharmaceuticals in Polish sewage are naproxen, a popular painkiller, and ofloxacin, an antibiotic. These compounds, found in rivers, lakes or seas, are persistent and not susceptible to biological degradation, and conventional methods used in sewage treatment plants are insufficient to remove them.
A promising way to remove pharmaceuticals from the aqueous phase is their degradation in the process of heterogeneous photocatalysis supported by peroxymonosulfate ions (HSO5−, PMS). These processes are based on the generation of highly reactive radicals under sunlight, which, as a result of reaction with pollutants, are able to purify water.
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