Synchrotron and neutron studies show cooking oil residues deposited on windows can harbour toxic chemicals
Aerosols contribute to ambient air pollution and, via processes such as cloud droplet formation, affect air quality and climate. Organic compounds often play a major role in aerosol composition, varying with time, location, season, and environment. Cooking food releases fatty acids into the air, and cooking emissions contribute around 10% to UK emissions of PM2.5 (aerosols up to two and a half microns wide). These aerosol particles can be deposited onto surfaces such as windows. A thin, layered film of material builds up over time, creating a persistent crust that is only slowly broken down by other chemicals in the atmosphere. In work recently selected as the best 2022 paper in Environmental Science: Atmospheres, a team led by researchers at the University of Birmingham created ultra-thin films, just a few tens of nanometres in thickness, approximating real-world pollution samples. Using X-ray and neutron techniques to study the nanoscale composition of the films and the changes in their surface structures as they aged, the researchers found that the self-organised layered structure can trap toxic pollutants and form a barrier that can prevent their breakdown. They also showed that the film’s surface becomes rougher and attracts more water from humidity, an effect with implications for the formation and lifetime of aerosols in the atmosphere.
It will be no surprise to anyone that cooking indoors releases particles that can make your kitchen windows dirty. Organic emissions from cooking include fatty acids, such as oleic acid, which are too stable to break down in the atmosphere. Oleic acid is also abundant in marine aerosol emissions, and the organic materials coating aerosol particles affect urban air quality. Indoors, atmospheric aerosols are deposited on surfaces, such as window glass, forming films.
In laboratory experiments, oleic acid is often used as a proxy, allowing researchers to study reactive organic aerosol systems. As a fatty acid surfactant, oleic acid can decrease the surface tension of a liquid, affecting an aerosol particle’s ability to take up water and form a cloud droplet. Like soap, oleic molecules have both water-attracting and water-repelling sections, allowing them to form lyotropic liquid crystals (LLCs). At a relative humidity of around 50%, they can also form layered stacks. These distinct molecular arrangements have different viscosity and diffusivity, both factors affecting the ageing of atmospheric particles.
In this study, the research team created ultra-thin oleic acid-sodium oleate films on solid silicon substrates and subjected them to oxidation and humidity changes that simulate atmospheric ageing. They used a combination of optical microscopy, neutron reflectometry (NR) (at ISIS and ILL) and grazing-incidence small-angle X-ray scattering (GI-SAXS) on Diamond’s I22 beamline to study changes in the surface structure of the films as they aged.
NR can probe the structure of interfaces, providing depth-resolved structural information and data on the thickness, roughness and density of each interfacial layer. GI-SAXS is a closely-related surface technique used to probe the surface morphology of materials.
Commonly used to determine the self-assembly and self-organisation of thin films at the nanoscale, GISAXS can measure X-ray scattering over a larger angular range and off-specular scattering (in the y-direction). In this work, it allowed the research team to determine the orientation of the layered stacks.
Dr Nick Terrill is the Principal Beamline Scientist for I22. He says:
This was a challenging experiment to set up, the first of its kind on I22, and involved a close collaboration to develop the sample environment, a humidity chamber that allowed us to do these experiments in situ. Most of the work we do on I22 looks at bulk samples, so it was an exciting development for us to look at the surface of these materials and use I22 to collect high-quality GI-SAXS data.
Read more on Diamond website
Image: Graphical abstract from the paper
