LAAAMP-Funded Team Makes a Journey of Miles and Nanometers

This is a story of miles and nanometers. Celline Awino Omondi and Miller Shatsala traveled from Kakamega, Kenya, to Berkeley, USA, through a grant from Lightsources for Africa, the Americas, Asia, Middle East, and Pacific (LAAAMP), a journey of over 9,400 miles. Their research interests, however, are best described with nanometers—very thin perovskite films to be used for solar energy.

At their home institution, Masinde Muliro University of Science and Technology, Omondi is a faculty member and Shatsala is a PhD student in the department of physics. Omondi’s interest in new materials began in graduate school. “I did a master’s in materials nanotechnology, and it was so interesting, I wanted to continue in materials science,” she said. Though her doctoral studies were in Germany, her research inspiration was closer to home. “In Africa, we have abundant solar radiation. So, we are looking for a way to tap into that solar radiation so that we can use it for our daily life.”

Omondi envisions many applications for photovoltaics. With the new materials under development, solar energy could be used in the future for everything from household electricity to vaccine storage in hospitals and irrigation on farms. New materials to harness solar energy would be life changing. “Most parts of Africa aren’t on the grid, and if they have electricity, it’s very expensive,” Omondi explained.

Similarly, Shatsala’s master’s thesis research focused on silicon solar cells. “Then I discovered that there are new materials coming up in solar energy whose efficiency was almost passing silicon, so that’s why I shifted to perovskites,” he said. 

To characterize the perovskites they’re studying, the two researchers came to the Advanced Light Source through a LAAAMP Faculty-Student (FAST) Teams grant. The program provides financial support for PhD students and their faculty advisors from Africa, the Caribbean, Mexico, Central Asia, Southeast Asia, the Middle East, and Pacific to spend two months in residence at a collaborative partner light source. With this training opportunity, scientists like Omondi and Shatsala will be able to take their newfound skills and knowledge back to a region that is still in the planning phases for its own synchrotron facility. One day in the future, the two researchers could be part of operating and using this facility—the African Light Source. “We were privileged to be picked to be among the few people in Africa to come to the ALS,” said Shatsala.

Read more on the ALS website

Image: The researchers at Beamline 7.3.3. Left to right: Yunfei Wang, Aidan Coffey, Miller Shatsala, Celline Omondi, Chenhui Zhu

Success from widening access to basic science research tools and synchrotron expertise in Africa

A focus of UNESCO’s International Year of Basic Sciences for Sustainable Development is ‘enhancing inclusive participation in science’. Diamond Light Source was a key partner in START, a collaborative project that sought to foster the development of Synchrotron Techniques for African Research and Technology (START), which ran from 2018 to 2021 with a £3.7 M grant from the Global Challenges Research Fund (GCRF) provided by the UK’s Science and Technology Facilities Council (STFC). Today on World Science Day for Peace and Development, we are highlighting health and energy research enabled by START.

Diamond played a pivotal role in the project, providing African scientists with crucial access to world class synchrotron techniques, beamtime, training and mentoring. Research focused on structural biology and energy materials to address key United Nations’ Sustainable Development Goals for health (SDG 3), energy (SDG 7), climate (SDG 13), and life-long learning (SDG 4).

Addressing worldwide energy challenges

Catalysis is essential for the development of a sustainable world and was a focus of the energy materials arm of the grant, along with solar energy, which is a well-recognised sustainable energy solution. These are just two areas in the physical sciences that were investigated as part of START.

Working towards better renewable energy solutions

Catalysis has many applications in renewable energy, where waste biomass is converted to liquid biofuels, or waste CO2 is converted to high value chemicals that can be used in our daily life, or as an alternative to fossil fuels. These applications rely on catalysts but to make this process more sustainable and efficient, advanced techniques are required to understand how the catalysts work under operating conditions. A group of START collaborators used Diamond to understand more about catalyst materials. They were investigating furfural, a bio-derived molecule that can be converted to many useful products that can be used for renewable energy. However, bio-derived compounds are highly functionalised – many parts of the molecular structure can undergo chemical change. Palladium (Pd) nanoparticles are widely used as an active component in furfural hydrogenation – a specific type of reaction that involves the addition of hydrogen to a compound – however, selectivity to specific products is a big challenge. Using X-ray absorption spectroscopy at Diamond, the team demonstrated that a Pd/NiO catalyst can hydrogenate furfural using a dual site process. This work has significant implications for the upgrading of bioderived feedstocks, suggesting alternative ways for promoting selective transformations and reducing the reliance on precious metals.

Read more on the Diamond website

Image: START logo