Targeted funding of innovation for the energy transition

LED lamps have seen rapid advances in recent years. PSI researcher Michael Weinold has been studying how this progress came about. One of the causes is spillover effects. These accelerate innovation and are important for the transformation of the energy system – and they can be deliberately promoted.

How do innovative ideas arise? If we knew the answer, we could produce a stream of new technologies. However for the most part, technological progress cannot be planned or else it follows a surprisingly circuitous path. Light-emitting diodes, or LEDs, are a particularly good example of this.

Michael Weinold is now a PhD student at the Laboratory for Energy Systems Analysis at PSI and the laboratory of the same name at ETH Zurich, working with Professor Russell McKenna. For his master’s thesis at the University of Cambridge and ETH Zurich he studied the rapid development of LEDs. He found that spillover effects were an important factor. In research, this term is used to describe advances or technologies that were originally developed for entirely different industries or products. The effect is particularly striking in the case of LEDs, as Weinold demonstrates in his paper. “Above all, the crucial improvement in the quality of the light is largely due to spillover effects,” says Weinold.

Michael Weinold’s research was conducted during his time as a visiting researcher at the Cambridge Centre for Environment, Energy and Natural Resource Governance (C-EENRG), in collaboration with Sergey Kolesnikov and Laura Diaz Anadon at the University of Cambridge. The work was part of a larger research project funded by the Alfred P. Sloan Foundation at the University of Cambridge, Harvard University and the University of Minnesota. The project set out to understand how innovation occurs in the energy system and how this process can be specifically accelerated by investing in fundamental research so as to reduce the energy consumption and emissions of new technologies.

Chance and targeted promotion

For decades, LEDs led a niche existence as red indicator lights on electrical appliances. That was until 1992, when Shuji Nakamura and his team came up with the first blue LED, the basis for today’s white LEDs and hence LED lighting in general. The scientists were awarded the Nobel Prize in Physics in 2014 for their work. Since then, there have been rapid improvements in production costs, efficiency and, above all, light quality. The cool LED light of the early days has given way to a pleasantly warm light, whereby the colour of the light can now be freely adjusted.

An example of a spillover effect for LEDs is indium tin oxide (ITO), a material that conducts electricity but is also transparent to light. It has long been used in the aviation industry to heat cockpit windows and so prevent ice from forming. Conductive and transparent – that was exactly what the developers of LEDs needed, and so ITO quickly found its way into their products.

“The great thing about spillover is that it’s free,” says Weinold, because the technology has already been developed and can often be used straight away in other areas. A spillover is often helped by chance. LEDs generate white light from blue light, which is converted by a thin phosphor coating. However, in the early days of LEDs, the only available phosphors produced a cool white light. It was not until a chance conversation between two professors at a conference that the door was opened for a spillover in phosphors. Since then, LEDs have also been able to produce a pleasant warm white light.

The catch is that if spillovers are not to be left to chance, researchers need to know exactly what they are looking for. For example, as long as the fundamental physical effects taking place in a diode are not fully understood, it is not possible to look for specific solutions that will produce higher efficiencies.

According to Weinold, this leads to an insight which ought to be of great interest particularly to those funding research. In order to accelerate the development of new technologies through spillover effects, it is necessary to specifically promote fundamental research. Ideally in those areas where physical or chemical mechanisms are not yet fully understood. Weinold explains: “Once the fundamental principles of a new technology have been properly studied, spillover effects are almost inevitable.”

The future of LEDs

It will be interesting to see how LEDs continue to evolve – if they do at all. In his research, Weinold found that almost all the physical processes involved in generating light with LEDs have come close to their theoretical maximum efficiency in recent years. The development of conventional LEDs could therefore slow down considerably over the coming years.

Nobel Prize winner Shuji Nakamura seems to have anticipated this. He has abandoned the development of conventional LEDs and is now conducting research into laser LEDs, a field in which considerable gains in efficiency are still expected. And major manufacturers such as Osram and Philips are focusing on developing special applications such as micro-LEDs for VR headsets. On the other hand, certain processes in LEDs have already achieved efficiencies of over 100 percent thanks to quantum mechanical effects. So further surprises should not be ruled out.

Read more on PSI website

Image: Spillover effects have led to rapid advances in the technology used for white light LEDs. Specifically funding fundamental research could increase similar effects in other areas, thereby accelerating innovative solutions for transforming the energy system. Michael Weinold from PSI has investigated how such spillover effects can be promoted.

Credit: Paul Scherrer Institute PSI/Mahir Dzambegovic

A faster route to green hydrogen

Acidic conditions are a challenge. If you want to produce hydrogen by electrolysis and use a low-cost catalyst such as cobalt, the process doesn’t function as well if the aqueous environment is acidic – working in alkaline conditions is easier. Researchers at the Paul Scherrer Institute PSI have now discovered the reason for this: the surface of the catalyst changes with the pH value of the environment. Their study, published in the journal Nature Chemistry, provides important clues to enable efficient and cost-effective production of hydrogen for the energy transition in the future.

The simplest and most environmentally friendly method for producing hydrogen is electrolysis: with an electric current, water (H2O) is split into its components, hydrogen (H) and oxygen (O2). Oxygen is produced at the positive pole, the anode; hydrogen is produced at the negative pole, the cathode. Water splitting can be carried out in an alkaline environment (pH>7), an acidic one (pH<7), or a neutral one (pH=7). Different types of electrolysers operate at different pH values, that is, in different aqueous environments.

In splitting water, the formation of oxygen is the step that requires the most energy, effectively the bottleneck of the reaction. To make it possible to do this more efficiently and cost-effectively, catalysts such as the metal cobalt are used. However, electrolysis with cobalt only works satisfactorily in an alkaline environment; the reason for this was previously unknown.

A PSI research group in the Center for Energy and Environmental Sciences have now found out the cause: depending on the pH value, the catalyst’s surface changes. In acidic conditions, active sites where oxygen can be produced require more energy to form – as a result, electrolysis becomes slow and uneconomical. “We assume that this is the case not only with cobalt, but also with other metals that likewise perform less well in acidic conditions – such as manganese, iron, and nickel,” says Jinzhen Huang, a postdoctoral researcher in Emiliana Fabbri’s and Thomas Schmidt’s research group and first author of the study.

Cobalt as a low-cost alternative

At present, the noble metals iridium and ruthenium are usually used as catalysts for splitting water. Their activity changes only slightly depending on the pH value and therefore also work well in acidic environments. However, cobalt and other so-called transition metals are significantly cheaper and more abundant on Earth, which makes them particularly attractive for large-scale applications. “Replacing the noble metals with cobalt and other lower-cost metals is a major challenge,” Emiliana Fabbri explains. “Our findings are important steps on the way to that goal.”

Read more on PSI website

Image: Close-up of a glass vial containing a cobalt-based catalyst powder, captured in the lab at the Paul Scherrer Institute PSI. Researchers at the PSI Center for Energy and Environmental Sciences have discovered why this catalyst performs more efficiently in alkaline environments during hydrogen production.

Credit: Paul Scherrer Institute PSI/Mahir Dzambegovic