From greenhouse gases to plastics

New catalyst for recycling carbon dioxide discovered

Imagine if we could take CO2, that most notorious of greenhouse gases, and convert it into something useful. Something like plastic, for example. The positive effects could be dramatic, both diverting CO2 from the atmosphere and reducing the need for fossil fuels to make products.

A group of researchers, led by the University of Toronto Ted Sargent group, just published results that bring this possibility a lot closer.

Using the Canadian Light Source and a new technique exclusive to the facility, they were able to pinpoint the conditions that convert CO2 to ethylene most efficiently. Ethylene, in turn, is used to make polyethylene—the most common plastic used today—whose annual global production is around 80 million tonnes.

 

>Read more on the Canadian Light Source website

 

Atmosphere in X-ray light

Light from the particle accelerator helps to understand ozone decomposition

A new experimental chamber coupled to the Swiss Light Source (SLS), a large-scale research facility of the Paul Scherrer Institute PSI, allows researchers to recreate atmospheric processes in the laboratory through unprecedented precision analysis involving X-rays.

In their first experiments, researchers detailed how bromine molecules are formed in the air. These play an essential role in the decomposition of ozone in the lower layers of the atmosphere. With their results, the researchers have also made an important contribution to models designed to explain and predict changes in climate and air composition. In the future, the experimental setup will be available to researchers in all scientific fields and those particularly concerned with the chemistry of the atmosphere or other topics in energy and environmental research.

>Read More on the PSI website

Image: In the experimental chamber, a very thin vertical jet of water can be seen, which flows downward in the middle of the picture from a small tube. During the experiment, the chamber contains a gas mixture including ozone, which reacts on the surface with bromide in the water and produces bromine. As an intermediate step in the process, a short-lived compound of bromide and ozone is made, which was detected for the first time ever with the help of X-ray light from SLS. For this proof, the X-ray light knocked electrons out of the compound, and these made their way to the detector through an opening in the cone (to the left in this photo). (Photo: Paul Scherrer Institute/Mahir Dzambegovic)