Nanodiamonds (NDs) are under active investigation for their unique properties and potential applications in energy harvesting, quantum technologies, and nanomedicine. The surface chemistry of diamond nanoparticles strongly modifies their physico-chemical properties (semiconducting behavior, colloidal properties, interaction with water and light). The present study aims to perform a chemical analysis by X-ray photoemission spectroscopy of the ND shallow surface (i. e. the first atomic planes) surrounded with water molecules.
This was achieved on PLEIADES beamline at SOLEIL synchrotron by researchers from NIMBE (CEA-CNRS UMR) on isolated ND in an aerodynamic jet. Results showed for the first time the effect of residual water molecules on different ND surface chemistries.
The electronic properties of diamond nanoparticles (ND) are highly dependent on their surface chemistry (oxidized, hydrogenated). Such ND can be stabilized in water exhibiting different colloidal properties according to their chemistry. These ND colloids can be further used to activate chemical reactions under light: CO2 reduction, hydrogen production, pollutant degradation. The ND / water interface, involved in these reactions, is still under investigation. In this study, the scientists investigated by photoemission the shallow surface chemistry of ND surrounded with water molecules. The synchrotron X-ray beam allowed them to tune the incident photon energy to probe the first atomic layers of ND (here 0.3 nanometer).
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