Grape pomace, a waste of viticulture, is effective for nematode pest control on crops

Researchers from Universidad de Castilla la Mancha, Universidad Autónoma de Madrid and the Institute of Agricultural Sciences – CSIC proved the potential of wine production residues as biopesticides in agriculture, thus reducing the waste management problem and contributing to a circular economy. Their work shows that recycled biochar from grape pomace is effective to reduce the parasitic nematode infection of tomato plants in pots. Biochar characterization by synchrotron light infrared spectroscopy was performed at MIRAS beamline of the ALBA Synchrotron.

Cerdanyola del Vallès, 22nd November 2023 The large amount of grape waste generated after wine production can be transformed into a valuable product such as biochar, a form of charcoal. A new published study shows that biochar soil amendments can help to control the infection of a group of plant parasitic nematodes: the root-knot nematodes.

Nematodes are a big group of invertebrates also known as roundworms. They are among the most widespread pests and can be found in almost every crop worldwide, causing annual global agriculture losses of approximately $125 billion. In particular, root-knot nematodes parasite plants penetrating the roots and inducing knots or galls. The plant becomes their host and will nourish them until life cycle completion.

Root-knot nematode infection is difficult to eradicate and usually requires the use of toxic nematicides that are banned in most countries. In this sense, the research team, formed by scientists from the Universidad de Castilla la Mancha (UCLM), Universidad Autónoma de Madrid (UAM) and the Institute of Agricultural Sciences (ICA-CSIC), proposes the use of biochar as an environmentally friendly and economic alternative.

To run the studies, tomato plants were infected withMeloidogyne javanica, a root-knot nematode, and grown in hydroponic system over a clay sandy substrate mixed with different proportions of biochar. After several days of post-inoculation, nematode infection progression was analysedThe infective and reproductive traits of a Meloidogyne javanica population in tomato were significantly reduced (egg masses and eggs per plant) for the biochar pyrolyzed at 350ºC.

In parallel, researchers performed a complete characterization of biochar after a thermal treatment (pyrolysis at 350ºC and 700ºC) by determining their elemental composition and analysing the particulate structure. To do so they use, among other techniques, infrared spectroscopy at MIRAS beamline of ALBA. The analysis with synchrotron light enabled scientist to visualize the large changes in the biomolecular composition of biochar, occurring during grape pomace pyrolysis.

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Synthesised a new catalyst with key properties to solve environmental issues

A research led by the ITQ-CSIC-UPV has discovered a new catalyst enabling hydrogenation of carbon dioxide to methane with advantages not seen until now. This new catalyst, whose structure and mechanism have been understood by synergistically exploiting different ALBA Synchrotron techniques, can be used for methane (natural syngas) production, that is considered as a promising energy carrier for hydrogen storage.

Linear economy has proven to be unsustainable in the long run due to its ineffective use of natural resources that leads to a huge amount of greenhouse gas emissions and waste generation. An alternative model, the so-called circular economy is based on an efficient production cycle that focuses on minimising waste and better recycling and seems to be key to find solutions for the climate crisis. One process that can be essential in this challenge is carbon dioxide (CO2) sequestration and usage, that is, transform atmospheric or produced carbon dioxide into energy carriers or platform molecules of the chemical industry.

An international collaboration between the Instituto de Tecnología Química – a join research center between Consejo Superior de Investigaciones Científicas and Universitat Politècnica de València (ITQ-CSIC-UPV), SOLEIL SynchrotronUniversidad de Cádiz, and ALBA Synchrotron permitted to synthesize a new catalyst able to hydrogenate carbon dioxide to methane with significant improvements in comparison to existing analogues. Its main advantage is that it possesses a much higher activity and so the reaction temperature can be lowered from usual 270-400ºC to only 180ºC, with an excellent long-term stability. Furthermore, this catalyst is able to operate under intermittent power supply conditions, which couples very well with electricity production systems based on renewable energies. Moreover, its synthetic procedure itself is ecofriendly, making it an even greater option in environmental issues.

This new catalyst can be used for methane (natural syngas) production, that is considered as a promising energy carrier for hydrogen storage.

The new solid catalyst was designed and synthesized in the ITQ (CSIC-UPV) by a mild, green hydrothermal synthesis procedure resulting in a material that contains interstitial carbon atoms doped in the ruthenium (Ru) oxide crystal lattice, enabling the stabilization of Ru cations in a low oxidation state with the formation of a none yet reported ruthenium oxy-carbonate phase.

Read more on ALBA website