Giving solid-state batteries a squeeze keeps them from short-circuiting

SLAC and Stanford researchers found that compressing solid-state battery material reduced the formation of lithium-filled intrusions called dendrites, leading to faster charging and longer battery life.

Key takeways:

  • A SLAC/Stanford University research team found they could prevent short-circuiting of solid-state batteries by deflecting the dendrite propagation direction using mechanical compression.
  • They provided direct evidence that dendrites start in the interior rather than merely at the surface of the electrolyte, settling a long-standing debate within the field.
  • The results could have implications for future battery design, by incorporating built-in mechanical compression or electrolytes with more defect-free interiors that suppress dendrite initiation.

Lithium-ion batteries power transportation and grid storage and enable our digital lives, but these ubiquitous batteries require frequent recharging and can fail over time.    

To make batteries more reliable and longer lasting, researchers are exploring how to replace liquids inside batteries with a solid ceramic substance that could improve their performance. 

But researchers must first overcome a big problem: cracks filled with lithium that form within the solid material during charging, causing the batteries to quickly short-circuit. When that happens, devices powered by these batteries become useless.

Researchers have long debated whether these cracks and the lithium metal inside them, called dendrites, form at the surface or inside the solid material – a key insight needed to figure out how to stop them from forming.

Now, in a study published in the journal Nature, researchers have discovered a way to track these dendrites and suppress them enough to keep the battery from short-circuiting.

Read more on the SLAC website

A simple chemical tweak to make sodium-ion batteries last longer

A research team led by CIC energiGUNE, in collaboration with the ALBA Synchrotron, has shown through multi-scale X-ray analysis that partially replacing manganese (Mn) with iron (Fe) in Prussian white —a low-cost green battery material— prevents structural degradation and paves the way for sustainable and long-lasting batteries.

Building cheaper, greener batteries is only half the challenge; making them last through hundreds of charge–discharge cycles is equally critical. A team of researchers from Spain and France, led by CIC energiGUNE, has tackled this problem in sodium-ion (Na-ion) batteries by improving Prussian white, an easy-to-synthesize, environmentally friendly material. Using the ALBA Synchrotron, they have discovered how a simple chemical modification can dramatically extend battery lifespan.

For Na-ion batteries to compete with lithium-ion technology —the current prevailing technology— highly cost efficient and more sustainable cathode materials are needed. Prussian white materials containing manganese (Mn) are particularly promising because their performance rivals that of lithium batteries. Their Achilles’ heel, however, is poor long-term durability. During charging, Mn undergoes oxidation, which triggers a local structural distortion. This distortion causes large volume changes, leading to severe structural degradation and rapid capacity loss.

The research team hypothesized that partially replacing Mn with iron (Fe) could stabilize the material over time. The results were striking: the modified material retained 93% of its original charge capacity after 50 cycles, compared to just 62% for the unaltered version. But the real breakthrough was understanding why.

Read more on the ALBA website

Battery Scientist Honored by DOE’s Vehicle Technologies Office

UPTON, N.Y. — Longer lasting batteries would allow electric vehicles (EVs) to drive farther and perhaps inspire more people to make the switch from fossil fuels. One key to better EV batteries is understanding the intricate details of how they work — and stop working.

Xiao-Qing Yang, a physicist who leads the Electrochemical Energy Storage group within the Chemistry Division at the U.S. Department of Energy’s (DOE) Brookhaven National Laboratory, has spent a good deal of his professional career doing just that. DOE’s Vehicle Technologies Office (VTO) recently recognized his contributions with a Distinguished Achievement Award presented during its 2024 Annual Merit Review. Each year, VTO presents awards to individuals from partner institutions for contributions to overall program efforts and to recognize research, development, demonstration, and deployment achievements in specific areas. 

Yang was honored “for pioneering [the use of] advanced characterization tools, such as in situ X-ray diffraction and absorption, to analyze battery materials under operational and extreme conditions in support of VTO battery research and development (R&D) at Brookhaven National Laboratory over the last 38 years.”

Read more on BNL website

Image: Battery chemist Xiao-Qing Yang (left) with colleagues Enyuan Hu and Eli Stavitski at the Inner-Shell Spectroscopy (ISS) beamline of the National Synchrotron Light Source-II at Brookhaven National Laboratory

Credit: Brookhaven National Laboratory