Tag: rare earth elements

Recovering in-demand metals for new electronics

Recovering in-demand metals for new electronics

Nearly all technology today—from cellphones to computers to MRI scanners—contains rare earth elements (REEs). The global market for REEs is predicted to reach $6.2 billion (USD) this year and $16.1 billion (USD) by 2034.

High concentrations of one particular REE — lanthanum — are often in find in mine tailings. Runoff from this waste can make its way into nearby bodies of water where it poses a risk to human health and the environment. As a result, researchers are on the hunt for ways to recover the material.

Michael Chan, working under the supervision of Dr. Huu Doan in the Department of Chemical Engineering at Toronto Metropolitan University (TMU), recently discovered that industrial-strength chemical adsorbents can be used to “soak up” lanthanum from that mine waste.

“These ‘fancy sponges’ are about the size of a grain of salt,” says Chan, who is completing his Masters degree at TMU. Working in a lab, Chan and his colleagues found that the metal ions present in a sample of contaminated water trade places with the hydrogen ions present on the surface of adsorbent.

When they filtered the adsorbent out of the water, they were left with cleaner water and recovered lanthanum that could be reformed and reused in new electronics.

The team used a scanning electron microscope at TMU to better understand the ion exchange process, then used the Canadian Light Source at the University of Saskatchewan to get even more detailed images and to confirm their findings.

Read more on CLS website

Recovering rare earth elements from coal ash for clean energy technologies

Recovering rare earth elements from coal ash for clean energy technologies

As the world transitions away from fossil fuels, the demand for rare earth elements (REEs) is only going to increase. These elements are vital to the production of technologies that will make the transition to green energy possible. While REEs are not technically rare, large deposits are found in only a few locations around the world – mostly in China – and they are difficult to extract.

“If we want to switch to electric vehicles by 2035 and be net-zero by 2050 we’re going to need new sources of these metals,” says Brendan Bishop, a PhD candidate studying REEs at the University of Regina.

Bishop and his colleagues have been studying one potential new source of these valuable elements: the ash that is produced as waste from coal-fired power plants. Researchers have looked into REEs in coal waste in the United States and China, but there has been little work done on ash from Canadian coal.

The team analyzed samples of ash from coal plants in Alberta and Saskatchewan to determine how much REEs the ashes contained, and how they could be extracted. While the concentration of REEs in Canadian coal ash is on par with that found in ash from other parts of the world, questions remained about whether the REEs are dispersed evenly throughout the ash particles or concentrated in certain minerals found within the ashes.

Using the powerful X-ray beamlines at the Canadian Light Source (CLS) at the University of Saskatchewan (USask), Bishop probed the ash, in search of a rare earth element called yttrium. They found it was distributed in specific mineral phases within the ash particles, most often in the form of silicates or phosphates such as xenotime which remain unchanged when the coal is burned.  The work was published in Environmental Science and Technology.

Read more on CLS website

A new way to control the magnetic properties of rare earth elements

A new way to control the magnetic properties of rare earth elements

The special properties of rare earth magnetic materials are due to the electrons in the 4f shell. Until now, the magnetic properties of 4f electrons were considered almost impossible to control. Now, a team from HZB, Freie Universität Berlin and other institutions has shown for the first time that laser pulses can influence 4f electrons- and thus change their magnetic properties. The discovery, which was made through experiments at EuXFEL and FLASH, opens up a new way to data storage with rare earth elements.

The strongest magnets we know of are based on rare earths. Their 4f electrons are responsible for their magnetic properties: they generate a large magnetic moment that is maintained even when their chemical environment changes. This means that rare earths can be used in very different compounds and alloys without changing their special magnetic properties. Until now, it was assumed that the magnetic properties of 4f electrons could not be changed even if the material was excited with a laser pulse. But indeed, this is possible, as a team from HZB, Freie Universität Berlin, DESY, the European X-ray laser XFEL and other institutions has now shown: The spatial arrangement of the 4f electrons can be briefly switched by laser excitation. This also changes their magnetism. This effect opens up new possibilities for the fast and energy-efficient control of magnetic rare-earth materials. The work has now been published in the journal Science Advances.

Read more on HZB website

Image: The image shows the terbium orbitals between which the excitation takes placeand a schematic sketch of the excitation process. 

Credit: HZB