Tag: clean energy

Toward greener production of hydrogen

Toward greener production of hydrogen

McGill researchers improve efficiency, stability of electrolysis process

Hydrogen fuel could be an important part of the clean energy revolution. But it faces some challenges. Most hydrogen today is made from natural gas using a process called steam methane reforming, which produces lots of carbon dioxide.

“While hydrogen is a clean fuel, the way that we make it isn’t clean at all,” says Hamed Heidarpour, a PhD student in Ali Seifitokaldani’s Electrocatalysis Lab at McGill University in Montreal.

Creating hydrogen from water through electrolysis, on the other hand, generates no CO2. But the method is inefficient, expensive, and requires a lot of electricity, which doesn’t always come from renewable sources.

Heidarpour and his colleagues found a way to make the process more energy-efficient and stable – and thus more viable for real-world industrial applications.

Their version of electrolysis combines water with hydroxymethylfurfural (HMF), an organic compound that can be produced by breaking down non-food plant materials such as pulp and paper residue. In traditional electrolysis, hydrogen is produced at the cathode, and oxygen at the anode. But the reaction – called the oxygen evolution reaction (OER) — is slow and takes a lot of energy. By including an organic molecule like HMF, the OER is replaced with the more energy-efficient oxidation of HMF, which has the bonus of also producing hydrogen.

“At the same energy input, we can double the production of hydrogen,” he says.

Heidarpour focused on designing a better catalyst to make the HMF oxidation reaction even more energy-efficient, and more commercially viable. The normal copper catalyst does not last long enough for long-term use, so the team added a protective layer of chromium to stabilize it. Their research was published in Chemical Engineering Journal.

Read more on the CLS website

Image: Hamed in the lab

Credit: CLS

Recovering rare earth elements from coal ash for clean energy technologies

Recovering rare earth elements from coal ash for clean energy technologies

As the world transitions away from fossil fuels, the demand for rare earth elements (REEs) is only going to increase. These elements are vital to the production of technologies that will make the transition to green energy possible. While REEs are not technically rare, large deposits are found in only a few locations around the world – mostly in China – and they are difficult to extract.

“If we want to switch to electric vehicles by 2035 and be net-zero by 2050 we’re going to need new sources of these metals,” says Brendan Bishop, a PhD candidate studying REEs at the University of Regina.

Bishop and his colleagues have been studying one potential new source of these valuable elements: the ash that is produced as waste from coal-fired power plants. Researchers have looked into REEs in coal waste in the United States and China, but there has been little work done on ash from Canadian coal.

The team analyzed samples of ash from coal plants in Alberta and Saskatchewan to determine how much REEs the ashes contained, and how they could be extracted. While the concentration of REEs in Canadian coal ash is on par with that found in ash from other parts of the world, questions remained about whether the REEs are dispersed evenly throughout the ash particles or concentrated in certain minerals found within the ashes.

Using the powerful X-ray beamlines at the Canadian Light Source (CLS) at the University of Saskatchewan (USask), Bishop probed the ash, in search of a rare earth element called yttrium. They found it was distributed in specific mineral phases within the ash particles, most often in the form of silicates or phosphates such as xenotime which remain unchanged when the coal is burned.  The work was published in Environmental Science and Technology.

Read more on CLS website

Team engineers nanoparticles using ion irradiation to advance clean energy and fuel conversion

Team engineers nanoparticles using ion irradiation to advance clean energy and fuel conversion

The work demonstrates control over key properties leading to better performance.

The following feature story was originally issued by the Massachusetts Institute of Technology (MIT). Adrian Hunt and Iradwikanari Waluyo helped reveal the electronic structure in the surface and bulk of  these nanoparticles using depth-sensitive soft x-ray absorption spectroscopy (XAS) performed at the In situ and Operando Soft X-ray Spectroscopy (IOS) beamline at the National Synchrotron Light Source II (NSLS-II), a U.S. Department of Energy (DOE) Office of Science User Facility at DOE’s Brookhaven National Laboratory. For more information on Brookhaven’s role in this research, contact Denise Yazak (dyazak@bnl.gov, 631-344-6371).

MIT researchers and colleagues have demonstrated a way to precisely control the size, composition, and other properties of nanoparticles key to the reactions involved in a variety of clean energy and environmental technologies. They did so by leveraging ion irradiation, a technique in which beams of charged particles bombard a material.

They went on to show that nanoparticles created this way have superior performance over their conventionally made counterparts.

“The materials we have worked on could advance several technologies, from fuel cells to generate CO2-free electricity to the production of clean hydrogen feedstocks for the chemical industry [through electrolysis cells],” says Bilge Yildiz, leader of the work and a professor in MIT’s departments of Nuclear Science and Engineering and Materials Science and Engineering.

Read more on the BNL website

Image: Artist’s representation of nanoparticles with different compositions created by combining two techniques: metal exsolution and ion irradiation. The different colors represent different elements, such as nickel, that can be implanted into an exsolved metal particle to tailor the particle’s compositions and reactivity.

Credit: Jiayue Wang

LCLS-II ushers in a new era of science

LCLS-II ushers in a new era of science

SLAC fires up the world’s most powerful X-ray laser

With up to a million X-ray flashes per second, 8,000 times more than its predecessor, it transforms the ability of scientists to explore atomic-scale, ultrafast phenomena that are key to a broad range of applications, from quantum materials to clean energy technologies and medicine.

The newly upgraded Linac Coherent Light Source (LCLS) X-ray free-electron laser (XFEL) at the Department of Energy’s SLAC National Accelerator Laboratory successfully produced its first X-rays, and researchers around the world are already lined up to kick off an ambitious science program. 

The upgrade, called LCLS-II, creates unparalleled capabilities that will usher in a new era in research with X-rays. Scientists will be able to examine the details of quantum materials with unprecedented resolution to drive new forms of computing and communications; reveal unpredictable and fleeting chemical events to teach us how to create more sustainable industries and clean energy technologies; study how biological molecules carry out life’s functions to develop new types of pharmaceuticals; and study the world on the fastest timescales to open up entirely new fields of scientific investigation. 

“This achievement marks the culmination of over a decade of work,” said LCLS-II Project Director Greg Hays. “It shows that all the different elements of LCLS-II are working in harmony to produce X-ray laser light in an entirely new mode of operation.”  

Reaching “first light” is the result of a series of key milestones that started in 2010 with the vision of upgrading the original LCLS and blossomed into a multi-year ($1.1 billion) upgrade project involving thousands of scientists, engineers, and technicians across DOE, as well as numerous institutional partners. 

“For more than 60 years, SLAC has built and operated powerful tools that help scientists answer fundamental questions about the world around us. This milestone ensures our leadership in the field of X-ray science and propels us forward to future innovations,” said Stephen Streiffer, SLAC’s interim laboratory director. “It’s all thanks to the amazing efforts of all parts of our laboratory in collaboration with the wider project team.”

Read more on the SLAC website

Image: The newly upgraded Linac Coherent Light Source (LCLS) X-ray free-electron laser (XFEL) at the Department of Energy’s SLAC National Accelerator Laboratory successfully produced its first X-rays. The upgrade, called LCLS-II, creates unparalleled capabilities that will usher in a new era in research with X-rays.

Credit: Greg Stewart/SLAC National Accelerator Laboratory

Superconducting X-ray laser reaches operating temperature colder than outer space

Superconducting X-ray laser reaches operating temperature colder than outer space

The facility, LCLS-II, will soon sharpen our view of how nature works on ultrasmall, ultrafast scales, impacting everything from quantum devices to clean energy.

Nestled 30 feet underground in Menlo Park, California, a half-mile-long stretch of tunnel is now colder than most of the universe. It houses a new superconducting particle accelerator, part of an upgrade project to the Linac Coherent Light Source (LCLS) X-ray free-electron laser at the Department of Energy’s SLAC National Accelerator Laboratory.

Crews have successfully cooled the accelerator to minus 456 degrees Fahrenheit – or 2 kelvins – a temperature at which it becomes superconducting and can boost electrons to high energies with nearly zero energy lost in the process. It is one of the last milestones before LCLS-II will produce X-ray pulses that are 10,000 times brighter, on average, than those of LCLS and that arrive up to a million times per second – a world record for today’s most powerful X-ray light sources.

“In just a few hours, LCLS-II will produce more X-ray pulses than the current laser has generated in its entire lifetime,” says Mike Dunne, director of LCLS. “Data that once might have taken months to collect could be produced in minutes. It will take X-ray science to the next level, paving the way for a whole new range of studies and advancing our ability to develop revolutionary technologies to address some of the most profound challenges facing our society.”

With these new capabilities, scientists can examine the details of complex materials with unprecedented resolution to drive new forms of computing and communications; reveal rare and fleeting chemical events to teach us how to create more sustainable industries and clean energy technologies; study how biological molecules carry out life’s functions to develop new types of pharmaceuticals; and peek into the bizarre world of quantum mechanics by directly measuring the motions of individual atoms.

A chilling feat

LCLS, the world’s first hard X-ray free-electron laser (XFEL), produced its first light in April 2009, generating X-ray pulses a billion times brighter than anything that had come before. It accelerates electrons through a copper pipe at room temperature, which limits its rate to 120 X-ray pulses per second.

Read more on the SLAC website

Uniting science to address climate change

Uniting science to address climate change

Key leaders and researchers from major US and European big science laboratories, namely EIROforum (Europe’s eight largest intergovernmental scientific research organisations, including CERN, EMBL, ESA, ESO, ESRF, EUROfusion, European XFEL and ILL) and the US Department of Energy’s seventeen National Laboratories (Ames, Argonne, Brookhaven, Fermi, Idaho, Jefferson, Los Alamos, Lawrence Berkeley, Lawrence Livermore, NETL, NREL, Oak Ridge, Pacific Northwest, PPPL, SLAC, Sandia and Savannah River), met by videoconference ahead of the United Nations Framework Convention on Climate Change Conference of Parties (COP26).

Sharing the same values, and convinced that science performs best through collaboration, the EIROforum’s directors and NLDC (comprised of directors from the US National Laboratories) affirmed their common commitment to unite science towards a sustainable and resilient global society and economy:

  • By stepping up their scientific collaboration on carbon-neutral energy and climate change
  • By sharing best practices to improve the climate sustainability and carbon footprint of Europe’s and US’s big science facilities
  • By sharing knowledge and fostering public engagement on clean energy and climate change research

Read more on the ESRF website

Image: COP26

Credit: ESRF