Safe and sustainable batteries focus for new university collaboration

A battery research collaboration focusing on lithium-ion alternatives is starting at MAX IV. The collaboration involving Swedish and Danish universities is a pilot for the new HUB user access mode.

Battery technology is an important Swedish and Nordic research area, something that has been underscored, not least by recent initiatives by the Swedish Government. The challenge of finding new, effective and sustainable lithium-ion battery alternatives is a complex and multifaceted task that requires collaboration between experts in different areas. This need motivated the new Battery pilot HUB, including Chalmers University of Technology, Uppsala University, Lund University, Aarhus University and MAX IV.

We spoke to Aleksandar Matic from Chalmers University of Technology, one of the partners in the newly formed Battery HUB collaboration named BatMAX and Joachim Schnadt, MAX IV Science Director.

“We’re going to study sodium-ion batteries, a promising battery technology for the future. Sodium-ion batteries can store about the same amount of energy as a conventional lithium-ion battery, but have several important advantages. Sodium is more abundant and evenly spread globally as a raw material since it can be extracted from seawater. Sodium-ion batteries are also more sustainable because the cathode materials do not contain cobalt, which is often used in lithium-ion battery cathodes,” says Matic.

Read more on the MAX IV website

Development of a methodology for the rapid determination of trace amounts of lead in cosmetic raw materials

The study was conducted by an interdisciplinary team of researchers from the SOLARIS National Synchrotron Radiation Centre, AGH University of Krakow, the Institute of Physics of the Jagiellonian University, and an industrial partner, Inglot Sp. z o.o. The aim of this work was to develop a rapid and sensitive method for the determination of trace amounts of lead in raw materials with potential cosmetic applications. The feasibility of using energy-dispersive X-ray fluorescence excited by monochromatic synchrotron radiation (SR-XRF) for the quantitative analysis of samples with complex and unknown matrices was evaluated. The use of synchrotron radiation enabled the achievement of very low detection limits with minimal sample preparation and short measurement times, and the results were validated using the ICP-OES method.

Cosmetic products play a significant role in human life, and their importance continues to increase alongside economic development and improved accessibility for various social groups. However, the growing number of consumers is accompanied by increasing concerns regarding cosmetic safety, particularly with respect to the presence of heavy metals. In the European Union, cosmetic products are regulated under Regulation (EC) No. 1223/2009, according to which lead and its compounds are listed as prohibited substances. Due to natural processes and the ubiquitous presence of ultra-low concentrations of elements in the environment, achieving their complete absence is not feasible, which necessitates the use of reliable and sensitive analytical methods enabling their control at trace levels.

Despite the existence of national recommendations concerning permissible heavy metal contents in cosmetics, harmonised international standards are still lacking. For example, in the United States and Canada a limit of 10 μg/g of lead is recommended, while in Germany the recommended limit is 5 μg/g. Heavy metals, including lead, may enter the human body via oral, inhalation or dermal routes, leading to bioaccumulation and serious adverse health effects, such as DNA damage, disruption of enzymatic activity, or abnormalities in calcium metabolism. Particular attention is given to products applied in the vicinity of the mouth and eyes, due to the risk of ingestion and the increased permeability of the thin skin in these areas.

Read more on the SOLARIS website

Image: Samples of cosmetic raw materials in tablet form just before XRF analysis on the POLYX beamline

The raw material detectives

New modeling methods and geochemical analyses provide information about deep deposits

The growing demand for raw materials makes mining unavoidable. The exploration of deposits increasingly relies on more environmentally friendly methods. In the European DeepBEAT project, scientists at the Helmholtz Institute Freiberg for Resource Technology (HIF), an institute of the Helmholtz-Zentrum Dresden-Rossendorf (HZDR), are pursuing the approach of using geochemical analyses to detect deep-seated ore deposits in a non-invasive manner. The researchers are testing the methods in three areas in Germany, the Czech Republic and Finland. The integrative involvement of all participants is an essential part of the project in order to improve mutual understanding in exploration projects. The EU is funding the three-year project with five million euros.

Our high-tech lifestyle is causing the raw materials consumption to rise continually. Despite intensive research into more effective processes, the demand cannot be met by recycling alone. At the same time, there is a growing awareness of our geopolitical responsibility regarding raw materials extraction. Both of these factors lead to the realization that raw materials must increasingly be extracted from European sources in a socially and environmentally responsible manner. New methods are needed to detect raw material-rich deposits in Europe – especially for deep-seated deposits, as neither geophysical nor geochemical signals from deep layers are easily distinguishable from signals close to the surface. To this end, scientists from six countries have joined forces to apply geochemical analysis methods for exploration and implement new forms of modeling in the European research project DeepBEAT (Deep exploration BoostEd by Advanced exploration Technologies).

Search for deep-seated deposits using geochemistry

Geochemistry is an important tool for many geoscientific questions. It provides insights into the material composition, distribution, stability, and cycle of chemical elements and their isotopes in minerals, rocks, soils, water, the Earth’s atmosphere, and the biosphere. “In geological exploration, geochemical approaches are typically used to analyze core samples in order to interpret information from depth. In the case of surface samples, geochemistry is traditionally applied to soil samples to detect, for example, abnormally high metal concentrations in soils. This typically only identifies near-surface ore deposits. Geochemical methods have been tested in a few studies to detect deeper deposits, and these have shown promising results,” explains Dr. Solveig Pospiech, project leader at HIF.

The detection of deep deposits is complicated by the distance between the surface and the ore body as a signal source. The challenge is to provide effective methods for improving the signal-to-noise ratio. These methods are intended to distinguish whether a measured signal originates from nearby sources – for example from outcropping rock or contamination from industrial activities – or from a deep source – i.e. a potential deposit. By tracing underground material cycles, scientists are gaining a better understanding of the geological situation. A key factor is selecting meaningful sampling points in the field and the materials to be sampled.

Read more on HZDR website

Image: Deep Exploration of concealed, deep-seated deposits of rare earth elements, cobalt and lithium boosted by advanced exploration technologies with geochemical methods at the surface

Credit: HZDR/Blaurock

Conversion of carbon dioxide into raw materials more effective with gold

Carbon dioxide, emitted mainly by combustion of fossil fuels, is harmful to the climate and the main reason for increased global warming. Diverting carbon dioxide into hydrogen carriers or chemicals such as methanol, a valuable raw material and energy carrier, is thus highly desired. Supported metal nanoparticle heterogeneous catalysts such as copper on zinc oxide is used for the catalytic conversion of carbon dioxide to methanol. Researchers have now discovered that it is possible to avoid by-products and at the same time make the process more sustainable by adding a small amount of gold to the catalyst.

Carbon dioxide can be converted into methanol and water by reaction with hydrogen. The reaction is only possible in the presence of a catalytic material such as Au or Cu nanoparticles supported on zinc oxide. The chemical reaction will then take place on the particle surfaces. In a recent study, a research team from Germany, Japan and Sweden have shown that modifying the typical ZnO-supported Cu nanoparticles by a small amount of gold (< 10 weight percent) makes the reaction more selective.

Read more on MAX IV website