Seawater: The next sustainable battery revolution

International team shows that with minor modifications chloride is effective electrode material for solid-state batteries

Seawater covers most of the globe and makes up around 97 per cent of all water on Earth. It could also hold the key to cheaper and greener batteries for storing green energy collected from wind turbines and solar cells.

Using the Canadian Light Source (CLS) at the University of Saskatchewan, an international research team involving scientists from Switzerland, Canada, and the United States, has shown that with some minor modifications, chloride – a sustainable and readily available component of seawater – could one day be the material that shuttles ions back and forth between the electrodes in solid-state batteries used for grid-scale energy storage.

Lithium is currently at the heart of modern batteries, powering everything from our smartphones to e-bikes and electric cars. But there’s a very real risk that the material could become scarcer and more expensive in the future. According to Natural Resources Canada, lithium production has more than doubled world-wide in in the past five years. And a handful of countries hold most of the planet’s lithium stores. Canada’s supplies amount to only 4.4 per cent of the total worldwide.

“We’re not looking to entirely replace lithium-ion batteries, but we need other solutions in the next few decades if we are going to meet this massive need that the world will have for hundreds of terawatt hours that allow for effective use of solar and wind,” said Sarbajit Banerjee, professor at ETH Zürich, a public university in Switzerland, and Head of the Laboratory for Battery Science at Switzerland’s Paul Scherrer Institute.

Read more on the CLS website

Image: Seaweed batteries – X-ray Excited Optical Luminescence Spectroscopy

Safe and sustainable batteries focus for new university collaboration

A battery research collaboration focusing on lithium-ion alternatives is starting at MAX IV. The collaboration involving Swedish and Danish universities is a pilot for the new HUB user access mode.

Battery technology is an important Swedish and Nordic research area, something that has been underscored, not least by recent initiatives by the Swedish Government. The challenge of finding new, effective and sustainable lithium-ion battery alternatives is a complex and multifaceted task that requires collaboration between experts in different areas. This need motivated the new Battery pilot HUB, including Chalmers University of Technology, Uppsala University, Lund University, Aarhus University and MAX IV.

We spoke to Aleksandar Matic from Chalmers University of Technology, one of the partners in the newly formed Battery HUB collaboration named BatMAX and Joachim Schnadt, MAX IV Science Director.

“We’re going to study sodium-ion batteries, a promising battery technology for the future. Sodium-ion batteries can store about the same amount of energy as a conventional lithium-ion battery, but have several important advantages. Sodium is more abundant and evenly spread globally as a raw material since it can be extracted from seawater. Sodium-ion batteries are also more sustainable because the cathode materials do not contain cobalt, which is often used in lithium-ion battery cathodes,” says Matic.

Read more on the MAX IV website

Green hydrogen from direct seawater electrolysis

At first glance, the plan sounds compelling: invent and develop future electrolysers capable of producing hydrogen directly from unpurified seawater. But a closer look reveals that such direct seawater electrolysers would require years of high-end research. And what is more: DSE electrolyzers are not even necessary – a simple desalination process is sufficient to prepare seawater for conventional electrolyzers. In a commentary in Joule, international experts compare the costs and benefits of the different approaches and come to a clear recommendation.

Fresh water is a limited resource; more than 96% of the world’s water is found in the oceans. If seawater could be fed directly into a future electrolyser to produce green hydrogen using renewable energy from the wind or sun, it sounds like a very good solution. Hundreds of millions of dollars in research fundingare spend for this idea and, in 2023 alone, there have been more than 500 publications (this number is growing exponentially) on direct seawater electrolysis.

No need for new development

However, a techno-economic analysis shows that this argument collapses as soon as the costs and benefits are analysed in more detail. “There is no convincing reason to develop DSE technology because there are already efficient solutions for using seawater to produce hydrogen,” says Dr Jan Niklas Hausmann, electrolysis researcher at HZB and lead author of the Joule commentary. International experts from various disciplines from renowned research institutions such as Yale University, universities in Canada, Germany and HZB contributed to the commentary.

Proven methods work

It is already possible to use seawater to produce hydrogen. Proven processes such as reverse osmosis can be used to purify seawater for “normal”, commercially available electrolysers. From a thermodynamic point of view, the purification of seawater needs only 0.03% of the energy required for its electrolysis. This is also reflected in the current cost: purifying seawater to produce one kilogram of hydrogen costs less than two cents. However, one kilogram of hydrogen costs 13.85 euros at German filling stations.

Read more on HZB website

Promising material provides a simple, effective method capable of extracting uranium from seawater

  • Uranium can be extracted from seawater simply and effectively using a new material
  • Adding neodymium to layered double hydroxides (LDHs) improved their ability to capture uranium selectively
  • Multiple techniques at ANSTO clarified the octahedral coordination environment, oxidation state and adsorption mechanism

An Australian-led international research team, including a core group of ANSTO scientists, has found that doping a promising material provides a simple, effective method capable of extracting uranium from seawater.

The research, published in Energy Advances and featured on the cover, could help in designing new materials that are highly selective for uranium, efficient, and cost-effective.

Read more on the ANSTO website

Producing hydrogen from seawater

McGill scientists have identified potential method for producing hydrogen from the oceans.

In her research on bone tissue engineering, Dr. Marta Cerruti has worked for years with graphene, a single sheet of carbon atoms with incredible properties – electrical conductivity and the ability to support tremendous weight. Now, her quest to improve its qualities has opened the door to a possible solution to one of the challenges of producing hydrogen from seawater.

Cerruti, a professor of materials engineering at McGill University, explained that while graphene is structurally sound, “one sheet of atoms is not something you can easily work with.” In fact, piling the sheets up results in, basically, pencil lead.

Searching for a way to make an easy-to-handle structure, Cerruti’s PhD student Yiwen Chen combined graphene with oxygen in a suspension with water to create reduced graphene oxide (GO), a porous, three-dimensional, electrically conductive scaffold. Cerruti suggested a further modification, with GO flakes stacked on the pore walls, “which allowed us to exploit another interesting property of GO – it creates a membrane that allows water through but no other molecules.”

When she canvassed her team for suggestions on how best to test the new scaffold, Gabriele Capilli, a post-doctoral fellow in her lab, suggested seawater electrolysis, a process similar to others he worked on while doing his PhD. It turns out the new GO “selective scaffold” has the potential to improve the process of producing hydrogen from the ocean. The team’s findings were published recently in the journal ACS Nano.

In conventional electrolysis, chloride ions in seawater penetrate the electrode and interact with the catalyst, creating hypochlorite ions, an unwanted byproduct that poisons the catalyst, Cerruti explained. Using X-ray phase contrast imaging at the Canadian Light Source at the University of Saskatchewan, Chen confirmed the GO scaffold had the right structure, with closed GO pores enclosing cobalt oxide nanoparticles as the catalyst. “We saw what we wanted to see.” Electrochemical tests performed in the laboratory of collaborator Thomas Szkopek (electrical engineering, McGill) confirmed the scaffold worked as expected to block unwanted ions.

Read more on the CLS website

Image: Gabriele Capilli, Marta Cerruti, and Thomas Szkopek (l to r), in their lab at McGill University.