Team engineers nanoparticles using ion irradiation to advance clean energy and fuel conversion

The work demonstrates control over key properties leading to better performance.

The following feature story was originally issued by the Massachusetts Institute of Technology (MIT). Adrian Hunt and Iradwikanari Waluyo helped reveal the electronic structure in the surface and bulk of  these nanoparticles using depth-sensitive soft x-ray absorption spectroscopy (XAS) performed at the In situ and Operando Soft X-ray Spectroscopy (IOS) beamline at the National Synchrotron Light Source II (NSLS-II), a U.S. Department of Energy (DOE) Office of Science User Facility at DOE’s Brookhaven National Laboratory. For more information on Brookhaven’s role in this research, contact Denise Yazak (dyazak@bnl.gov, 631-344-6371).

MIT researchers and colleagues have demonstrated a way to precisely control the size, composition, and other properties of nanoparticles key to the reactions involved in a variety of clean energy and environmental technologies. They did so by leveraging ion irradiation, a technique in which beams of charged particles bombard a material.

They went on to show that nanoparticles created this way have superior performance over their conventionally made counterparts.

“The materials we have worked on could advance several technologies, from fuel cells to generate CO2-free electricity to the production of clean hydrogen feedstocks for the chemical industry [through electrolysis cells],” says Bilge Yildiz, leader of the work and a professor in MIT’s departments of Nuclear Science and Engineering and Materials Science and Engineering.

Read more on the BNL website

Image: Artist’s representation of nanoparticles with different compositions created by combining two techniques: metal exsolution and ion irradiation. The different colors represent different elements, such as nickel, that can be implanted into an exsolved metal particle to tailor the particle’s compositions and reactivity.

Credit: Jiayue Wang

Promising material provides a simple, effective method capable of extracting uranium from seawater

  • Uranium can be extracted from seawater simply and effectively using a new material
  • Adding neodymium to layered double hydroxides (LDHs) improved their ability to capture uranium selectively
  • Multiple techniques at ANSTO clarified the octahedral coordination environment, oxidation state and adsorption mechanism

An Australian-led international research team, including a core group of ANSTO scientists, has found that doping a promising material provides a simple, effective method capable of extracting uranium from seawater.

The research, published in Energy Advances and featured on the cover, could help in designing new materials that are highly selective for uranium, efficient, and cost-effective.

Read more on the ANSTO website

Installation of SESAME’s HESEB soft X-ray beamline starts

From 9th to 27th January, a team from the German company FMB Feinwerk- und Meßtechnik GmbH in Berlin that was awarded the contract for construction of HESEB, the Helmholtz-SESAME Beamline for soft X-ray spectroscopy, together with SESAME’s team, installed the complete front-end and optics of the beamline at the ID 11 port of the SESAME ring.

In 2019, five research centers of the German Helmholtz Association, DESY (Deutsches Elektronen-Synchrotron), FZJ (Forschungszentrum Jülich), HZB (Helmholtz-Zentrum Berlin), HZDR (Helmholtz-Zentrum Dresden-Rossendorf), and KIT (Karlsruher Institut für Technologie), joined forces to implement a new, state-of-the-art soft X-ray beamline at SESAME. The HESEB project is being generously funded to the order of 3.5 M€ by the Initiative & Networking Fund of the Helmholtz Association.

The source will be a refurbished BESSY-II UE56 APPLE-II undulator provided by HZB.

HESEB will be the first soft X-ray beamline at SESAME and will significantly expand the research capabilities available to the user community in the Middle East and neighbouring regions. The undulator’s ability to provide linearly to circularly polarized light makes the beamline very suitable for materials science applications, especially magnetic materials. Its plane grating monochromator uses exchangeable gratings to cover a photon energy range from 70 eV to 2000 eV.

Image: The HESEB project team during installation at SESAME of the front-end and optics of the beamline

Credit: © SESAME 2022

Read more on the SESAME website and see a time-lapse video of the HESEB installation below: