Tag: batteries

Researchers find an inexpensive way to make batteries last longer

Researchers find an inexpensive way to make batteries last longer

By adjusting the heating process when making lithium-ion cathodes, the team created batteries that retained nearly 93% of their energy after 500 cycles.

Editor’s note: The following news brief was originally published by the U.S. Department of Energy’s (DOE) SLAC National Accelerator Laboratory. The research team used transmission X-ray microscopy at the Full Field X-ray Imaging (FXI) beamline at the National Synchrotron Light Source II (NSLS-II), a DOE Office of Science user facility at DOE’s Brookhaven National Laboratory, to visualize 3D changes in nickel oxidation states within individual particles of nickel-rich layered cathodes as they were heated. Understanding this process could help pave the way for longer-lasting battery structures.

To make batteries that last longer, scientists are creating internal battery structures that don’t degrade as quickly as current designs do. In fact, the reason many lithium-ion batteries ultimately fail is that their cathodes, or negative electrodes, crack after repeated charging and discharging.

Researchers at the SLAC-Stanford Battery Center, a partnership between Stanford University’s Precourt Institute for Energy and the Department of Energy’s SLAC National Accelerator Laboratory, have found a simple way to solve this problem in nickel-rich layered-oxide cathodes, the type of cathode used in powerful, long-lasting lithium-ion batteries for data centers and grid-scale energy storage.

By adjusting the heating process when making these cathodes – starting slowly, then ramping up the heat quickly – they found they could create more uniform cathode structures at the nanoscale level. These structures don’t crack and degrade as quickly as current batteries.

The resulting material was more resistant to strain and cracking, retaining nearly 93% of the battery’s energy after 500 cycles. 

Read more on the BNL website

Argonne celebrates successful completion of the APS Upgrade

Argonne celebrates successful completion of the APS Upgrade

The U.S. Department of Energy has granted its final approval to the project, bringing the decade-plus-long effort to a close

The upgraded APS is now the brightest synchrotron X-ray light source in the world, and extraordinary new scientific experiments are underway.

The comprehensive upgrade of the Advanced Photon Source (APS) is officially completed.

The U.S. Department of Energy (DOE) has given its final approval to the APS Upgrade Project, an $815 million effort to transform the APS into the brightest synchrotron X-ray facility in the world. The effort has taken more than a decade to plan and complete and has resulted in a facility with unprecedented capabilities for scientific discovery. The APS is a DOE Office of Science user facility at DOE’s Argonne National Laboratory.

The upgraded APS now generates X-ray beams that are up to 500 times brighter than before and sports nine new experiment stations (called beamlines) built to take full advantage of those enhanced beams. Scientists have been using the revamped facility for more than a year, exploring its new capabilities for research into more durable materials (for airplane turbines and other high-stress uses), longer-lasting batteries (for laptops and cell phones) and microelectronics (for our device-driven modern lives).

Read more on the Argonne website

Image: Advanced Photon Source

Credit: Argonne National Laboratory

Solid Electrolytes: A Breakthrough for Safer, High-Performance Batteries

Solid Electrolytes: A Breakthrough for Safer, High-Performance Batteries

Synchrotron studies shed light on new places to look for high ionic conductivity

Batteries are a critical technology for the transition to a sustainable energy economy. Rechargeable lithium ion (Li ion) batteries power our electronic devices and electric cars and are needed to store energy generated from renewable sources. The design and discovery of new materials underpins the development of high performing and reliable rechargeable batteries that are long-lasting, cost-effective, fast charging, safe and sustainable. Most Li-ion batteries rely on a liquid electrolyte to conduct ions between the anode and cathode. However, liquid electrolytes can leak and are flammable, which can lead to fires. One solution to this issue is to use a solid electrolyte, and researchers at the University of Liverpool have discovered a solid material with high enough Li ion conductivity to replace the liquid electrolytes in current Li ion battery technology, improving safety and energy capacity. Their work, recently published in Science, used a collaborative computational and experimental workflow, synthesising the material in the laboratory, using synchrotron techniques to determine its structure, and demonstrating it in a battery cell. Their disruptive design approach offers a new route to discover more high-performance materials that rely on the fast motion of ions in solids.

A New Pathway to Superionic Conductivity

If you’re looking for a new material for battery electrolytes, then you want something with high ionic conductivity and good chemical compatibility between the solid electrolyte and lithium metal is required. The existing high-performance solid-state electrolytes come from a small number of structural families with transport paths that minimize changes in cation coordination. With the assumption that this is what gives them their high conductivities, the search for new materials has continued along the same lines – emphasising anion packings that provide a single type of Li coordination environment

However, the team at the University of Liverpool has taken a different approach, opting for a design strategy using multiple anions to construct suitable pathways, supported by AI and physics-based calculations. The material they synthesised, Li7Si2S7I, is a pure lithium-ion conductor created by an ordering of sulphide and iodide with many different cation coordination environments that combine to create superionic conductivity. Created from non-toxic earth-abundant elements, the new material operates in a new way and achieves a high enough Li ion conductivity to replace liquid electrolytes.

At the start of the project, computational exploration of the Li-Si-S-I phase field offered up a number of candidate compositions, which were synthesised in carbon crucibles in the lab. Using X-ray Diffraction to identify the materials formed highlighted a novel phase. After suitable crystals for single-crystal diffraction were grown, the team used high resolution single-crystal XRD on Diamond’s I19 beamline to solve the crystal structure.

Read more on Diamond website

Image: The figure represents the lithium ions (in blue) moving through the structure

Credit: Liverpool University

Studying Interfacial Effects in Solid-Electrolyte Batteries

Studying Interfacial Effects in Solid-Electrolyte Batteries

At the Advanced Light Source (ALS), an ambient-pressure probe of a solid electrolyte revealed how surface electrochemical mechanisms lead to poor electrolyte performance and battery failure.

The results can help scientists engineer better coatings and interfaces, which are essential for building safer and better-performing batteries, particularly for use in vehicles.

A solid prospect for better batteries

Global efforts to electrify transportation and provide grid-level energy storage have driven demand for new battery technologies with improved safety, power density, and energy density. Ceramic solid electrolytes potentially offer significant advantages compared to the traditional liquid electrolytes used in lithium-ion batteries, including lower flammability and greater compatibility with high-energy electrode materials such as lithium metal. Among solid-electrolyte contenders, tantalum-doped lithium lanthanum zirconium oxide (LLZO) has garnered significant attention as a separator material because of its high bulk ionic conductivity and minimal chemical reactivity with lithium metal.

However, LLZO performance is limited by reactions that produce surface contaminants. Understanding the mechanisms behind these reactions is crucial for improving material processing. In this work, researchers used ambient-pressure x-ray photoelectron spectroscopy (APXPS) as part of a systematic investigation of the impacts of electrochemical reactions and contamination. The results will inform the design of safer and more-efficient batteries for electric vehicles or renewable energy storage.

Facing the interfacial challenges

It is well known that, in the presence of water vapor in air, LLZO undergoes Li+/H+ exchange, where protons (H+) can take up lithium-ion (Li+) sites without modifying the cubic crystal structure. This results in the formation of surface contaminants such as LiOH and Li2CO3 that contribute to poor interfacial contact and the constriction of current.

Numerous studies have explored different aspects of the surface contamination mechanisms on LLZO along with various processing techniques aimed at improving surface properties. However, most studies have focused on critical current density (CCD) tests, which provide limited mechanistic insight, or impedance analyses, with limited rationale behind their interpretation.

In this study, the researchers utilized a variety of surface-treatment processes on LLZO pellets to selectively induce proton exchange and contamination reactions in LLZO. The resulting bulk and surface chemistry was systematically characterized and correlated to changes in electrochemical properties.

ALS studies at ambient pressure

To observe the evolution of chemical species near the LLZO surface, ambient-pressure x-ray photoelectron spectroscopy (APXPS) was performed at ALS Beamline 9.3.2. The ability to tune the gas environment and temperature during measurement was crucial, as it allowed the researchers to optimize conditions (pressure, temperature, time) for removing surface contaminants. Also, the ability to vary the probe depth via beam energy was also essential for chemical speciation.

Read more on ALS website

Image: Illustrations of some of the surface treatments applied to a solid-state battery-electrolyte material (LLZO) as part of this study: glovebox polishing (Gb:Pol), heat treatment (HT), acid treatment (AT), water treatment (WT), and water treatment + heat treatment (WT:HT). Proton concentration (the result of H+ displacing Li+) is indicated by the color gradient, from low (orange) to high (blue). Pink and purple indicate surface contaminants.

RIXS Shows Why Li-rich Batteries Fade

RIXS Shows Why Li-rich Batteries Fade

High-resolution resonant inelastic X-ray scattering uncovers the role that oxygen plays in voltage fade in next-gen battery materials

As part of the transition to net zero, the Faraday Institution’s CATMAT (Lithium Ion Cathode Materials) project is focusing on improving lithium-ion battery energy density and electric vehicle (EV) range. Its scope includes adding to our understanding of lithium-rich (Li-rich) oxygen-redox cathodes and novel anion-chemistry cathodes, as well as developing scalable synthesis routes for these materials. As part of this project, researchers from the University of Oxford are working with Diamond’s I21 beamline to explore the cause of voltage fade in Li-rich cathodes, using high-resolution resonant inelastic X-ray scattering (RIXS) spectroscopy. In work recently published in Nature Materials, they followed the oxygen redox reaction in Li-rich cathodes over cycling and quantitatively measured the O2 trapped within the material. Their results show that a gradual increase in electrochemically inactive O2 and the loss of O2 from voids near the cathode surface lead to a reduction in the O redox capacity and the observed voltage fade. These important insights could lead to innovations in cathode chemistry and aid the transition to low-carbon energy sources. 

Powering net zero: understanding lithium-rich battery cathodes 

The net zero transition necessary to limit the effects of climate change requires dramatic cuts to carbon emissions. One of the cornerstones of the UK’s transition will be switching to fossil-free transport, with electric vehicles (EV) one of the most developed options. However, the cathode is a critical limiting factor in efforts to increase the energy density of lithium-ion (Li-ion) batteries for EV applications. As changes to the chemistry of the cathode are likely to lead to improvements in battery performance, such as boosting battery life, storing greater energy to improve range, reducing battery cost and increasing the power available to the EV during acceleration, developing next-generation lithium-ion cathodes is a major priority.  “Lithium-ion batteries are very critical to the net zero transition, enabling electric vehicles and grid storage, says Dr Robert House, at the University of Oxford.

In order to get better batteries, we need new materials which are able to store more energy in the same volume and the same mass – an increase the energy density. One of the biggest limitations is the cathode material. These typically have layered structures with alternating layers of transition metal oxide and lithium ions. The best-known cathode materials are NMCs, named for the combination of nickel, cobalt and manganese within the transition metal layer.

Dr Robert House

Lithium-rich cathodes are next-generation materials which have higher concentrations of lithium within the cathode structure, replacing some of the transition metals. They have a higher capacity because they store energy via oxidation of the oxygen in the structure as well as the transition metal. However, although these materials were first discovered over twenty years ago, a long-standing question has been how the oxygen undergoes charge storage. Dr House says:

Over the past few years, working on the CATMAT project, we’ve uncovered that the oxideoxygen anion converts to O2 molecules, which are trapped within the crystal structure of the cathode. And this discovery of the exact nature of the oxygen was first made possible by using high resolution RIXS on the I21 beamline.

Read more on Diamond website

Image: Imaging and measurements demonstrated the battery fade

Using sodium to make more sustainable batteries

Using sodium to make more sustainable batteries

The element lithium is used widely in batteries because it results in long-lasting, stable energy storage. However, it’s a finite resource, so researchers are hard at work trying to identify alternate materials to use in battery production. Using the Canadian Light Source at the University of Saskatchewan, a team from McGill University has recently come up with a way to replace most of the lithium in batteries with sodium.

The challenge with using sodium is that the cathode material becomes unstable when it’s exposed to air, a big problem if you want to retool existing manufacturing facilities currently producing lithium-ion batteries. “The sodium reacts with carbon dioxide and water vapour in the air, and it makes sodium carbonate and other products”, says Eric McCalla an associate professor in McGill’s Department of Chemistry. “Water can actually go into the material, and convert it into a completely different structure, which is not a good battery material.”

McCalla’s team used what he calls “wild substitutions,” to simultaneously test the impact of 52 different elements on the stability of a sodium-ion battery. The HXMA beamline at the CLS helped them see detailed, localized information about the battery after use, allowing them to understand which elements were effective in keeping the battery stable, when used alongside sodium.

Read more on CLS website

New process makes battery production more eco friendly

New process makes battery production more eco friendly

Switching from gas-powered cars to electric vehicles is one way to reduce carbon emissions, but building the lithium-ion batteries that power those EVs can be an energy-intensive and polluting process itself. Now researchers at Dalhousie University have developed a manufacturing process that is cheaper and greener.

“Making lithium-ion cathode material takes a lot of energy and water, and produces waste. It has the biggest impact on the environment, especially the CO2 footprint of the battery,” says Dr. Mark Obrovac, a professor in Dalhousie University’s Departments of Chemistry and Physics & Atmospheric Science. “We wanted to see if there were more environmentally friendly and sustainable – and less expensive – ways to make these materials.”

Most electric vehicle batteries use lithium nickel manganese cobalt oxide (NMC), with the elements mixed in the crystal structure of the cathode. They are typically made by dissolving the elements in water then using the crystals that form when the elements come together as a solid. That process takes a lot of water – which then has to be treated to clean it – and energy, which is the main source of the cost and carbon footprint of the batteries. Using the Canadian Light Source (CLS) at the University of Saskatchewan, Obrovac and his team investigated whether they could use an all-dry process to get the same results while saving energy, water, and money.

Their work has been published in two papers, in ACS Omega and the Journal of the Electrochemical Society.

“We wanted to see, can you get the same quality if you take dry materials and combine them using simple processes that you’d find in any large-scale factory and heat them up,” he says. “And under what conditions can you do that to get commercial-grade material while cutting out the water and the waste?”

Cathodes made from dry materials are sometimes not as homogeneous as those made in water, so the team tried a variety of methods using different oxides and heating regimes under different temperatures and pressures to determine what worked best.

Read more on CLS website

Image: A student making lithium batteries in a glove box for the evaluation of new cathode materials.

Credit: CLS

BESSY II: How pulsed charging enhances the service time of batteries

BESSY II: How pulsed charging enhances the service time of batteries

An improved charging protocol might help lithium-ion batteries to last much longer. Charging with a high-frequency pulsed current reduces ageing effects, an international team demonstrated. The study was led by Philipp Adelhelm (HZB and Humboldt University) in collaboration with teams from the Technical University of Berlin and Aalborg University in Denmark. Experiments at the X-ray source BESSY II were particularly revealing.

Ageing effects analysed

Lithium-ion batteries are powerful, and they are used everywhere, from electric vehicles to electronic devices. However, their capacity gradually decreases over the course of hundreds of charging cycles. The best commercial lithium-ion batteries with electrodes made of so-called NMC532 (molecular formula: LiNi0.5Mn0.3Co0.2O2) and graphite have a service life of up to eight years. Batteries are usually charged with a constant current flow. But is this really the most favourable method? A new study by Prof Philipp Adelhelm’s group at HZB and Humboldt-University Berlin answers this question clearly with no. The study in the journal Advanced Energy Materials analyses the effect of the charging protocol on the service time of the battery.

Part of the battery tests were carried out at Aalborg University. The batteries were either charged conventionally with constant current (CC) or with a new charging protocol with pulsed current (PC). Post-mortem analyses revealed clear differences after several charging cycles: In the CC samples, the solid electrolyte interface (SEI) at the anode was significantly thicker, which impaired the capacity. The team also found more cracks in the structure of the NMC532 and graphite electrodes, which also contributed to the loss of capacity. In contrast, PC-charging led to a thinner SEI interface and fewer structural changes in the electrode materials.

Read more on HZB website

Developing batteries with 10 times the energy storage

Developing batteries with 10 times the energy storage

Researchers from Western University gain deeper understanding of all-solid-state lithium-sulfur batteries, which could lead to EVs that cost less to purchase, travel further on a single charge, and are safer to drive.

To meet the rising global demand for electric vehicles, we need new and improved batteries. One promising candidate are all-solid-state lithium sulfur batteries. They can store nearly 10 times the amount of energy as traditional lithium-ion batteries, according to researcher Justin Kim.

This type of rechargeable battery uses sulfur, a material that is affordable, readily available, and more environmentally friendly, and it is also significantly safer, according to Kim. This means that your electric vehicle could cost less to purchase, drive longer distances on a single charge, and be a safer ride for your family.

“The fundamental understanding of this type of battery is very limited right now because it’s an emerging technology,” said Kim, who studied lithium sulfur batteries during his Master’s degree at Western University and is now working on his PhD at the University of California in Los Angeles in the same field. “So, not much is known about their operational mechanism and their failure modes, and this information is really important for designing longer-lasting, high-energy density batteries.”

Kim and colleagues at Western University used the Canadian Light Source (CLS) at the University of Saskatchewan to analyze what happens inside these batteries when they are in use. They identified which species of sulfur are formed in the battery during its operation and how this could reduce performance or cause the batteries to fail. Their findings were published in Nature Communications.

Read more on CLS website

A new approach to longer-lasting, faster-charging batteries

A new approach to longer-lasting, faster-charging batteries

Researchers from McGill University and Université du Québec à Montreal (UQAM) have found a new approach to making inexpensive batteries that can not only hold large amounts of charge but also recharge quickly.

Their work focuses on improving lithium ion batteries, rechargeable cells that are used in electric vehicles, power tools, phones and more.

“The work that we’ve done at the CLS is going to open up the door to be able to make batteries that can be charged faster, which will be one of the ways that we can start implementing them in real use cases as soon as possible,” says McGill researcher Jeremy Dawkins, the lead author of a recent paper on the work published in the journal ChemElectroChem.

To understand how a battery performs, researchers need to see what’s going on inside while it is being used. This is challenging to do in most labs, but the Canadian Light Source (CLS) synchrotron at the University of Saskatchewan (USask) offers the bright, intense x-ray light required to peer into a working battery.

Lithium ion batteries can be made of a combination of different materials, which researchers tweak to get the performance they want.

Read more on CLS website

What drives ions through polymer membranes

What drives ions through polymer membranes

Ion exchange membranes are needed in (photo)electrolysers, fuel cells and batteries to separate ions and enable the desired processes. Polymeric membranes such as synthetically produced compounds like NAFION are particularly efficient, but they cannot be degraded. A ban on the use of these “eternal chemicals” is currently under discussion in the European Union, and the development of suitable alternatives will be a major challenge. So, it is crucial to understand why NAFION and other established polymeric membranes work so well.

A team led by Dr. Marco Favaro of the HZB Institute for Solar Fuels has now investigated this using a special type of electrolysis cell. Here, the membrane sits on the outer wall and is in contact with both the liquid electrolyte and a gaseous external environment. It can act either as an anode or a cathode, depending on the polarity of the applied potential. This hybrid liquid-gas electrolyzer is considered particularly favorable for the electrochemical conversion of CO2 thanks to the higher CO2 concentrations that can be achieved in the gas phase, thereby overcoming the poor solubility of CO2 in aqueous solutions.

For the study, Favaro and his team used commercially available ion-exchange membranes in contact with a model electrolyte like sodium chloride (NaCl) in water. Water vapor was fed to the gas phase, with the partial pressure of water close to its vapor pressure at room temperature. To analyze the migration of sodium and chloride ions through the membrane, they used in situ ambient pressure hard X-ray photoelectron spectroscopy (AP-HAXPES) at the SpAnTeX end-station at the KMC-1 beamline of BESSY II.

“Indeed, we were expecting that the ion dynamics was determined, under applied potentials, by the electric fields generated between the anode and cathode of the electrolyzer, and that electromigration was therefore the main driver,” says Marco Favaro.

However, analysis of the data showed otherwise: electromigration hardly plays a role; the ions simply diffuse across the membrane. The data could be perfectly simulated numerically with a diffusion model. “Our conclusion is that ions move through the polymer membranes in these types of electrolyzers due to hopping mediated by the ionized functional groups present in the membranes. In addition, since water diffuses as well through the polymer, the ions are “dragged” as well” explains Favaro.

These results are exciting for a number of reasons: These types of electrolyzers are a way to convert CO2 into valuable chemicals that can otherwise only be obtained from fossil fuels. Understanding how these devices work helps on the way to decarbonize the economy. On the other hand, the ion-exchange membranes that are a key component of these cells are themselves problematic: the European Union may soon ban the use of persistent chemicals. Understanding the relevant drivers of such transport processes will help to develop new membrane materials that are both efficient, durable, and environmentally friendly. Favaro now intends to take this project forward at HIPOLE, the new Helmholtz Institute in Jena, which will focus on polymer materials for new energy technologies.

Read more in the Journal of Materials Chemistry A

Image: Membrane

Credit: HZB

New study could help unlock ‘game-changing’ batteries for electric vehicles and aviation

New study could help unlock ‘game-changing’ batteries for electric vehicles and aviation

Significantly improved electric vehicle (EV) batteries could be a step closer thanks to a new study led by University of Oxford researchers, published today in Nature. Using advanced imaging techniques, this revealed mechanisms which cause lithium metal solid-state batteries (Li-SSBs) to fail. If these can be overcome, solid-state batteries using lithium metal anodes could deliver a step-change improvement in EV battery range, safety and performance, and help advance electrically powered aviation.

One of the co-lead authors of the study Dominic Melvin, a PhD student in the University of Oxford’s Department of Materials, said:

Progressing solid-state batteries with lithium metal anodes is one of the most important challenges facing the advancement of battery technologies. While lithium-ion batteries of today will continue to improve, research into solid-state batteries has the potential to be high-reward and a gamechanger technology.

Li-SSBs are distinct from other batteries because they replace the flammable liquid electrolyte in conventional batteries with a solid electrolyte and use lithium metal as the anode (negative electrode). The use of the solid electrolyte improves the safety, and the use of lithium metal means more energy can be stored. A critical challenge with Li-SSBs, however, is that they are prone to short circuit when charging due to the growth of ‘dendrites’: filaments of lithium metal that crack through the ceramic electrolyte. As part of the Faraday Institution’s SOLBAT project, which Diamond is a partner, researchers have led a series of in-depth investigations to understand more about how this short-circuiting happens.

In this latest study, the group used an advanced imaging technique called X-ray Computed Tomography (X-ray CT) at the I13-2 beamline of Diamond Light Source to visualise dendrite failure in unprecedented detail during the charging process.

Read more on the Diamond website

A first step to designing better solid-state batteries

A first step to designing better solid-state batteries

Electrifying transportation is an essential step towards mitigating climate change. To improve the power, efficiency and safety of electric vehicles, researchers must continue to develop better batteries. All-solid-state lithium batteries (SSBs), which have a solid electrolyte instead of a liquid, are safer than traditional lithium-ion batteries because they are less flammable and more stable at higher temperatures. They could also have higher energy densities than lithium-ion batteries, allowing for longer lasting batteries in smaller sizes for portable electronics and other applications.

A research team led by Joshua Gallaway of Northeastern University in Boston and scientists at the Department of Energy’s (DOE) Argonne National Laboratory recently tested how the composition of thick cathodes affected electrochemical reactions in SSBs. The team used the resources of the Advanced Photon Source (APS), a DOE Office of Science user facility at Argonne. Their discoveries were published in the journal ACS Energy Letters.

“How all-solid-state batteries are designed will determine what their applications will be and how they will be optimized moving forward,” — Josh Gallaway, Northeastern University

Gallaway relates batteries to sandwiches — they are comprised of an anode on one side, a cathode on the other, a separator in the middle, and electrolyte solution throughout. When batteries provide power, lithium ions flow from the anode to cathode through the electrolyte. While SSBs don’t require traditional separators because the electrolyte separates the anode and cathode, they do require thick cathodes.

In this study, Gallaway and his colleagues evaluated batteries with thick cathodes that were comprised of two materials: a sulfide solid electrolyte called LPSC and an NMC (nickel, manganese, cobalt) cathode active material (CAM). They altered the composition of these two materials, so some batteries were 80% CAM, 20% LPSC, while others were 70% CAM, 30% LPSC and 40% CAM, 60% LPSC. Then, they used X-ray imaging and scattering at APS beamline 6-BM-A to measure six slices within the cathode and solid-state electrolyte.

Read more on the Argonne website

Image: An all-solid-state battery on an experimental stage used in the study. The battery is compressed in a vise and has a laser shining on it to align the X-ray beam.

Credit: Josh Gallaway/Northeastern University, Boston.

The APS prepares for its renewal

The APS prepares for its renewal

The facility’s ultrabright X-ray beams will turn off for a year to enable a comprehensive upgrade, one that will light the way to new breakthroughs

With the start of the construction period, the Advanced Photon Source is now only a year away from re-emerging as a world-leading X-ray light source. Its brighter beams will lead to new discoveries in energy storage, materials science, medicine and more.

Today, a year-long effort to renew the Advanced Photon Source (APS), a U.S. Department of Energy (DOE) Office of Science user facility at DOE’s Argonne National Laboratory, officially begins.

After years of planning and preparation, the team behind the APS Upgrade project will now spend the next 12 months removing the old electron storage ring at the heart of the facility, replacing it with a brand new, state-of-the-art storage ring and testing the new ring once it is in place. The team will also build seven new experiment stations, construct the needed infrastructure for two more and update nearly every existing experiment station around the APS ring.

This is an extensive project, representing an $815 million investment from DOE. When complete, the APS will re-emerge as a world leader in global hard X-ray synchrotron science, enabling unimaginable new discoveries. Science conducted at the APS will lead to longer-lasting, faster-charging batteries, more durable airplane engines and better treatments for infectious diseases, among many other discoveries.

“The APS Upgrade is not only an investment in the facility’s future, but in the next 25 years of advancements that will change the way we power our vehicles, harness renewable energy and learn more about the fundamental science that underpins our future technologies.” — Linda Horton, associate director of science for Basic Energy Sciences, U.S. Department of Energy.

“This is a significant day for Argonne,” said Argonne Director Paul Kearns. ​“The APS Upgrade will transform the future of science for America and the world. Once we safely complete construction, the APS will shed new light on how the brain works, develop materials to decarbonize our economy, refine quantum technologies that can power the internet of the future and answer many other questions in numerous other disciplines.”

Read more on the Argonne National Laboratory website

Image: The Advanced Photon Source is undergoing a comprehensive upgrade that will result in X-ray beams that are up to 500 times brighter than the current facility can create. After a year-long shutdown, the upgraded APS will open the door to discoveries we can barely imagine today

Credit: Argonne National Laboratory/JJ Starr

New SLAC-Stanford Battery Center targets roadblocks to a sustainable energy transition

New SLAC-Stanford Battery Center targets roadblocks to a sustainable energy transition

The center at SLAC aims to bridge the gaps between discovering, manufacturing and deploying innovative energy storage solutions. 

The Department of Energy’s SLAC National Accelerator Laboratory and Stanford University today announced the launch of a new joint battery center at SLAC. It will bring together the resources and expertise of the national lab, the university and Silicon Valley to accelerate the deployment of batteries and other energy storage solutions as part of the energy transition that’s essential for addressing climate change.

A key part of this transition will be to decarbonize the world’s transportation systems and electric grids ­– to power them without fossil fuels. To do so, society will need to develop the capacity to store several hundred terawatt-hours of sustainably generated energy. Only about 1% of that capacity is in place today.

Filling the enormous gap between what we have and what we need is one of the biggest challenges in energy research and development. It will require that experts in chemistry, materials science, engineering and a host of other fields join forces to make batteries safer, more efficient and less costly and manufacture them more sustainably from earth-abundant materials, all on a global scale. 

The SLAC-Stanford Battery Center will address that challenge. It will serve as the nexus for battery research at the lab and the university, bringing together large numbers of faculty, staff scientists, students and postdoctoral researchers from SLAC and Stanford for research, education and workforce training. 

 “We’re excited to launch this center and to work with our partners on tackling one of today’s most pressing global issues,” said interim SLAC Director Stephen Streiffer. “The center will leverage the combined strengths of Stanford and SLAC, including experts and industry partners from a wide variety of disciplines, and provide access to the lab’s world-class scientific facilities. All of these are important to move novel energy storage technologies out of the lab and into widespread use.”

Expert research with unique tools

Research and development at the center will span a vast range of systems – from understanding chemical reactions that store energy in electrodes to designing battery materials at the nanoscale, making and testing devices, improving manufacturing processes and finding ways to scale up those processes so they can become part of everyday life. 

“It’s not enough to make a game-changing battery material in small amounts,” said Jagjit Nanda, a SLAC distinguished scientist, Stanford adjunct professor and executive director of the new center, whose background includes decades of battery research at DOE’s Oak Ridge National Laboratory. “We have to understand the manufacturing science needed to make it in larger quantities on a massive scale without compromising on performance.”

Longstanding collaborations between SLAC and Stanford researchers have already produced many important insights into how batteries work and how to make them smaller, lighter, safer and more powerful. These studies have used machine learning to quickly identify the most promising battery materials from hundreds made in the lab, and measured the properties of those materials and the nanoscale details of battery operation at the lab’s synchrotron X-ray facility. SLAC’s X-ray free-electron laser is available, as well, for fundamental studies of energy-related materials and processes. 

SLAC and Stanford also pioneered the use of cryogenic electron microscopy (cryo-EM), a technique developed to image biology in atomic detail, to get the first clear look at finger-like growths that can degrade lithium-ion batteries and set them on fire. This technique has also been used to probe squishy layers that build up on electrodes and must be carefully managed, in research performed at the Stanford Institute for Materials and Energy Sciences (SIMES).

Nanda said the center will also focus on making energy storage more sustainable, for instance by choosing materials that are abundant, easy to recycle and can be extracted in a way that’s less costly and produces fewer emissions.

Read more on the SLAC website

Improving the production of batteries for electric vehicles

Improving the production of batteries for electric vehicles

A research lead by the company BASF has characterized a new methodology to produce nickel-rich cathode materials used in lithium-ion batteries that optimizes the conventional production process. The proposed model leads to an increase in throughput by a factor of three, representing a considerable increase in the efficiency of future cathode active materials production for battery electric vehicles. The contributions of the MSPD beamline at ALBA have been key in these findings.

Batteries of electric vehicles still have not reached full cost competitiveness with respect to cars powered by combustion engines. This is mainly due to the increase in the cost of the raw materials used to produce the cathode of the batteries. In the search for low-cost materials for cathodes, the research on efficient manufacturing is of utmost importance.

A research led by the company BASF, in collaboration with different German universities and research centers, has studied how to optimize the conventional production process of nickel-rich cathode materials for lithium-ion batteries. This process is a thermal treatment called calcination. More specifically, researchers wanted to obtain a deeper understanding of the lithiation mechanism itself. And also, whether a two-stage calcination process, including a partial-lithiation step, can be used to synthesize cathode active materials with similar properties to those of a conventional one-stage calcination protocol.

The proposed calcination concept leads to an increase in throughput by a factor of three, increasing the efficiency of future cathode active materials production without modifying their physico-chemical properties and electrochemical behavior. Moreover, further advantages of the partial-lithiation process regarding homogeneity of the composition and crystallite size of the cathode active materials are believed to come into view as soon as large-scale sample amounts are investigated, which will be part of future work.

To further characterize the samples after the partial-lithiation step, synchrotron X-ray powder diffraction (XRD) measurements were performed at the MSPD beamline of the ALBA Synchrotron. This is the first report on the composition of the lithium-containing residual needles, which are indicative of an incomplete reaction. By combination of XRD, and other characterization techniques, the presence of Lithium hydroxide was confirmed in the samples prepared with the conventional method but not on the samples obtained with the novel two-stage methodology.

Read more on the ALBA website