A breakthrough cyanide-bridged molecular magnet

Researchers at the Jagiellonian University have developed a new Prussian Blue analogue that exhibits ferrimagnetic ordering at a record-high temperature exceeding 400 K (127 °C). The discovery, reported in the Advanced Science article “Heavy Prussian Blue Analog with Magnetic Ordering above 400 K”, concerns a cyanide-bridged molecular magnet composed of vanadium(II) and molybdenum(III) ions, which replace the traditional iron ions found in the Prussian Blue structure. The experimental work described in the publication was carried out at SOLARIS on the ASTRA beamline.

The study reports the synthesis, structural analysis and magnetic characterisation of the amorphous compound {[K(crypt222)]0.34VII1.37MoIII(CN)6(BF4)0.08·xCH3CN} n(VII–MoIII(CN)6), demonstrating its ferrimagnetic behaviour up to 400 K (127 °C) – a temperature range previously inaccessible for conventional cyanide–bridged magnets.

Read more on the SOLARIS website

Image: A single frame from the video illustrating the behaviour of VII–CrIII(CN)6 in a varying magnetic field between 0 and 0.5 T.

 Turning Non-Magnetic Materials Magnetic with Atomically Thin Films

The rules about magnetic order may need to be rewritten. Researchers have discovered that chromium selenide (Cr₂Se₃) – traditionally non-magnetic in bulk form – transforms into a magnetic material when reduced to atomically thin layers. This finding contradicts previous theoretical predictions, and opens new possibilities for spintronics applications. This could lead to faster, smaller, and more efficient electronic components for smartphones, data storage, and other essential technologies.

An international research team from Tohoku University, Université de Lorraine (Synchrotron SOLEIL), the National Synchrotron Radiation Research Center (NSRRC), High Energy Accelerator Research Organization, and National Institutes for Quantum Science and Technology successfully grew two-dimensional Cr₂Se₃ thin films on graphene using molecular beam epitaxy. By systematically reducing the thickness from three layers to one layer and analyzing them with high-brightness synchrotron X-rays, the team made a surprising discovery. This finding challenges conventional theoretical predictions that two-dimensional materials cannot maintain magnetic order.

“When we first observed the ferromagnetic behavior in these ultra-thin films, we were genuinely shocked,” explains Professor Takafumi Sato (WPI-AIMR, Tohoku University), the lead researcher. “Conventional theory told us this shouldn’t happen. What’s even more fascinating is that the thinner we made the films, the stronger the magnetic properties became—completely contrary to what we expected.”

While three-dimensional Cr₂Se₃ crystals exhibit antiferromagnetism (where magnetic moments cancel each other out), the two-dimensional versions transform into ferromagnetic materials. Even more remarkably, the ferromagnetic transition temperature increases as the films become thinner.

Through micro-ARPES analysis of electronic states, researchers identified the mechanism behind this phenomenon: conduction electrons injected from the graphene substrate across the interface into Cr₂Se₃ are the decisive factor enabling high-temperature ferromagnetism in these ultra-thin films.

Read more on KEK website

Image: In 1966, Mermin and Wagner theoretically predicted that while ferromagnetic order can be stabilized in three-dimensional systems, it cannot be sustained in two-dimensional isotropic systems due to thermal fluctuations (left: 3D, right: 2D).

Credit: Takafumi Sato et al.

Research confirms antiferromagnetic order in real quasicrystals

ANSTO was part of a team led by researchers from Tokyo University of Science and Tohoku University, who have discovered antiferromagnetism in a real icosahedral quasicrystal (iQC), reinvigorating the search for antiferromagnetic quasicrystals.

Quasicrystals (QCs) are fascinating solid materials that exhibit an intriguing atomic arrangement. Unlike regular crystals, in which atomic arrangements have an ordered repeating pattern, QCs display long-range atomic order that is not periodic. Due to this ‘quasiperiodic’ nature, QCs have unconventional symmetries that are absent in conventional crystals. 

Since their discovery in 1984, which was recognized by the Nobel Prize in 2011, quasicrystals have captured considerable attention among condensed matter physics researchers not only for their potential to realize unique quasiperiodic magnetic order but also for their possible applications in spintronics and magnetic refrigeration.

Even though ferromagnetism was recently discovered in the gold-gallium-rare earth (Au-Ga-R) icosahedral QCs, its observation may not be entirely unexpected in the condensed matter physics community, as translational periodicity is not a prerequisite for the emergence of ferromagnetic order. In contrast, antiferromagnetism, the other fundamental type of magnetic order found in nature, is inherently more sensitive to crystal symmetry. 

Although its establishment in certain types of QCs has long been anticipated by theoreticians, it has not been directly observed in real QCs. Experimentally, most magnetic iQCs exhibit spin-glass-like freezing behaviour, with no sign of long-range magnetic order, which has led researchers to question whether antiferromagnetism is even compatible with quasiperiodicity—until now.

The research team was led by Professor Ryuji Tamura from the Department of Materials Science and Technology at Tokyo University of Science (TUS), along with Mr. Takaki Abe, also from TUS, Professor Taku J. Sato from Tohoku University, and Professor Max Avdeev from the Australian Nuclear Science and Technology Organisation and The University of Sydney.

 “As was the case for the first report of antiferromagnetism in a periodic crystal in 1949, we present the first experimental evidence of antiferromagnetism occurring in an iQC,” says Prof. Tamura. Their study was published in the journal Nature Physics.

“This is a very important development, that is attracting considerable scientific interest.  Neutron scattering experiments on the Echidna instrument at the Australian Centre for Neutron Scattering provided definitive evidence of long-range antiferromagnetic ordering in the Au–In–Eu sample”, said Prof Avdeev.

“Neutron diffraction will be equally important in the studies of other magnetic quasicrystals in the follow-up studies.”

Read more on ANSTO website

Image: First direct observation of antiferromagnetism in an icosahedral quasicrystal (iQC)

Credit: Ryuji Tamura from Tokyo University of Science, Japan

BESSY II: Heterostructures for Spintronics

Spintronic devices work with spin textures caused by quantum-physical interactions. A Spanish-German collaboration has now studied graphene-cobalt-iridium heterostructures at BESSY II. The results show how two desired quantum-physical effects reinforce each other in these heterostructures. This could lead to new spintronic devices based on these materials.

Spintronics uses the spins of electrons to perform logic operations or store information. Ideally, spintronic devices could operate faster and more energy-efficiently than conventional semiconductor devices. However, it is still difficult to create and manipulate spin textures in materials.

Graphene for Spintronics

Graphene, a two-dimensional honeycomb structure build by carbon atoms, is considered an interesting candidate for spintronic applications. Graphene is typically deposited on a thin film of heavy metal. At the interface between graphene and heavy metal, a strong spin-orbit coupling develops, which gives rise to different quantum effects, including a spin-orbit splitting of energy levels (Rashba effect) and a canting in the alignment of spins (Dzyaloshinskii-Moriya interaction). Especially the spin canting effect is needed to stabilise vortex-like spin textures, known as skyrmions, which are particularly suitable for spintronics.

Plus Cobalt Monolayers

Now, however, a Spanish-German team has shown that these effects are significantly enhanced when a few monolayers of the ferromagnetic element cobalt are inserted between the graphene and the heavy metal (here: iridium). The samples were grown on insulating substrates which is a necessary prerequisite for the implementation of multifunctional spintronic devices exploiting these effects.

Read more on HZB website

Image: Symbolic illustration of a graphene layer on a microchip. In combination with a heavy-metal thin film and ferromagnetic monolayers, graphene could enable spintronic devices.

Credit: Dall-E/arö

A Novel Staircase Pattern in Spin-Stripe Periodicity

SCIENTIFIC ACHIEVEMENT

At the Advanced Light Source (ALS), striped patterns of spins in a magnetic thin film were found to evolve under an applied magnetic field in steps reminiscent of a structure known as the “Devil’s Staircase.”

SIGNIFICANCE AND IMPACT

Such studies are valuable for understanding competing interactions at the atomic level for applications such as magnetic sensors and spintronic devices.

Devilishly complex systems

The “Devil’s Staircase” is a peculiar mathematical function that rises continuously but has no slope (i.e., its derivative is zero almost everywhere). This is because it consists of “runs” (flat sections) connected by “rises” that are fractal: each contains successively smaller copies of the main step, to the infinitesimal limit. Similar structures have emerged in phenomena ranging from earthquakes to charge density waves—systems characterized by competing pressures that result in periods of stability punctuated by short bursts of activity.

Here, researchers report the observation of novel staircase patterns in the evolution of spin-stripe domains in an iron/gadolinium (Fe/Gd) multilayer system. Theoretical modeling that builds on the measurements revealed which of the competing atomic-level interactions in this system is the dominant cause of the staircase structure. The findings help unravel the complex interplay of forces affecting spins in systems relevant to applications in magnetic sensing, information storage, and spintronics.

Read more on the ALS website

Image: A scattering image of one of the sample’s magnetic phases

Spintronics: A new path to room temperature swirling spin textures

A team at HZB has investigated a new, simple method at BESSY II that can be used to create stable radial magnetic vortices in magnetic thin films.

In some materials, spins form complex magnetic structures within the nanometre and micrometre scale in which the magnetization direction twists and curls along specific directions. Examples of such structures are magnetic bubbles, skyrmions, and magnetic vortices. Spintronics aims to make use of such tiny magnetic structures to store data or perform logic operations with very low power consumption, compared to today’s dominant microelectronic components. However, the generation and stabilization of most of these magnetic textures is restricted to a few materials and achievable under very specific conditions (temperature, magnetic field…).

A new approach

An international collaboration led by HZB physicist Dr Sergio Valencia has now investigated a new approach that can be used to create and stabilize complex spin textures, such as radial vortices, in a variety of compounds. In a radial vortex, the magnetization points towards or away from the center of the structure. This type of magnetic configuration is usually highly unstable. Within this novel approach radial vortices are created with the help of superconducting structures while their stabilization is achieved by the presence of surface defects.

Superconducting YBCO-islands

Samples consist of micrometer size islands made of the high-temperature superconductor YBCO on which a ferromagnetic compound is deposited. On cooling the sample below 92 Kelvin (-181 °C), YBCO enters the superconducting state. In this state, an external magnetic field is applied and immediately removed. This process allows the penetration and pinning of magnetic flux quanta, which in turn creates a magnetic stray field. It is this stray field which produces new magnetic microstructures in the overlying ferromagnetic layer: spins emanate radially from the structure centre, as in a radial vortex.

Read more on HZB website

Altermagnetism proves its place on the magnetic family tree

There is now a new addition to the magnetic family: thanks to experiments at the Swiss Light Source SLS, researchers have proved the existence of altermagnetism. The experimental discovery of this new branch of magnetism is reported in Nature and signifies new fundamental physics, with major implications for spintronics.

Magnetism is a lot more than just things that stick to the fridge. This understanding came with the discovery of antiferromagnets nearly a century ago. Since then, the family of magnetic materials has been divided into two fundamental phases: the ferromagnetic branch known for several millennia and the antiferromagnetic branch. The experimental proof of a third branch of magnetism, termed altermagnetism, was made at the Swiss Light Source SLS, by an international collaboration led by the Czech Academy of Sciences together with Paul Scherrer Institute PSI.

The fundamental magnetic phases are defined by the specific spontaneous arrangements of magnetic moments – or electron spins – and of atoms that carry the moments in crystals. Ferromagnets are the type of magnets that stick to the fridge: here spins point in the same direction, giving macroscopic magnetism. In antiferromagnetic materials, spins point in alternating directions, with the result that the materials possess no macroscopic net magnetisation – and thus don’t stick to the fridge. Although other types of magnetism, such as diamagnetism and paramagnetism have been categorised, these describe specific responses to externally applied magnetic fields rather than spontaneous magnetic orderings in materials.

Altermagnets have a special combination of the arrangement of spins and crystal symmetries. The spins alternate, as in antiferromagnets, resulting in no net magnetisation. Yet, rather than simply cancelling out, the symmetries give an electronic band structure with strong spin polarization that flips in direction as you pass through the material’s energy bands – hence the name altermagnets. This results in highly useful properties more resemblant of ferromagnets, as well as some completely new properties.

A new and useful sibling

This third magnetic sibling offers distinct advantages for the developing field of next-generation magnetic memory technology, known as spintronics. Whereas electronics makes use only of the charge of the electrons, spintronics also exploits the spin-state of electrons to carry information.

Although spintronics has for some years promised to revolutionise IT, it’s still in its infancy. Typically, ferromagnets have been used for such devices, as they offer certain highly desirable strong spin-dependent physical phenomena. Yet the macroscopic net magnetisation that is useful in so many other applications poses practical limitations on the scalability of these devices as it causes crosstalk between bits – the information carrying elements in data storage.

More recently, antiferromagnets have been investigated for spintronics, as they benefit from having no net magnetisation and thus offer ultra-scalability and energy efficiency. However, the strong spin-dependent effects that are so useful in ferromagnets are lacking, again hindering their practical applicability.

Here enter altermagnets with the best of both: zero net magnetisation together with the coveted strong spin-dependent phenomena typically found in ferromagnets – merits that were regarded as principally incompatible.

“That’s the magic about altermagnets,” says Tomáš Jungwirth from the Institute of Physics of the Czech Academy of Sciences, principal investigator of the study. “Something that people believed was impossible until recent theoretical predictions is in fact possible.”

Read more on PSI website

Image: Juraj Krempasky, scientist at PSI and first author of the Nature publication. The experimental proof of altermagnetism was made at the SIS (COPHEE endstation) and ADRESS beamlines of the SLS.

Credit: Paul Scherrer Institut / Mahir Dzambegovic

Extreme Domain Wall Speeds Observed in Ferromagnets

The manipulation of magnetic domains is of paramount interest because of its potential applications in spintronics and next generation technologies for mass storage. In current storage devices, such as hard disk drives, information is processed using either magnetic fields or spin currents. However, existing technologies are limited in speed, not only due to engineering factors but also because of fundamental limits in driving domain walls at high speed. The motion of domains driven using conventional magnetic field and spin currents is limited to a speed of about 0.5 km/s, due to the phenomenon named Walker breakdown. Above this threshold speed, domains become unstable and develop different spin dynamics. Interestingly, recent theoretical investigations have predicted that speeds exceeding 10 km/s are achievable in ferromagnetic materials when driven by an optical laser pulse.

In this work, we optically excited a CoFe/Ni multilayer sample and measured the ultrafast response of magnetic domains using small angle X-ray scattering at Diffraction and Projection Imaging (DiProI) beamline of the FERMI free electron laser. 

Read more on Elettra website

Image: Experimental schematic and evolution of labyrinthine domain pattern as a function of delay time. (a) Optical pump – EUV magnetic scattering probe experimental setup with highlighted an MFM image of the domain sample pattern. The white arrow indicates the preferential direction of the linear texture of the domain pattern. Magnetic diffraction scattering on the CCD is fitted with a 2D phenomenological model, from which we separate the ring and lobe components. (b) Isolated isotropic (ring) and anisotropic (lobes) fit components with arrows indicating the radius (qR, qL) and full-width half maximum (ΓR, ΓL) of scattering. Time-resolved (a) amplitude (AR), (b) ring radius (qR), and (c) width (ΓR) obtained from the fit of the isotropic scattering (ring). Delay curves are plotted for a range of measured fluence values from 0.8 to 13.4 mJ/cm2. The scattering amplitude, which is proportional to magnetization, decays immediately following laser excitation indicating demagnetization which recovers on picosecond timescales. The ring radius (qR) and width (ΓR) of the isotropic scattering approximate the average real-space domain size and correlation length of the labyrinthine domains, respectively.

Ultrafast all-optical spin injection in silicon revealed at FERMI

A revolutionary and energy-efficient information technology encoding digital data in electron spin (spintronics) by combining semiconductors and ferromagnets is being developed worldwide. Merging of memory and logic computing of magnetic based storage devices and silicon-based logic transistors is expected to ultimately lead to new computing paradigms and novel spin-based multifunctional devices. The advantages of this new technology would be non-volatility, increased data processing speed, reduced electric power consumption. All of them are essential steps towards next generation quantum computers.

To create spin-based electronics with potential to revolutionize information technology, silicon, the predominant semiconductor, needs to be integrated with spin functionality. Although silicon is non-magnetic at equilibrium, spin polarized currents can be established in Si by a variety of approaches such as the use of polarized light, hot electrons spin injection, tunnel spin injection, Seebeck spin tunneling and dynamical spin pumping methods, as had been demonstrated recently. In general, spin polarized currents refer to the preferential alignment of the spin angular momentum of the electrons in a particular direction.

Read more on the Elettra website

Image: Figure 1: a) the optical generation of spin polarized superdiffusive currents across a ferromagnetic/semiconductor interface is illustrated. b) the principles of TR-MOKE experiment are illustrated  together with a cross-section TEM image describing the quality of the Ni/Si interface.

Spintronics: A new tool at BESSY II for chirality investigations

Information on complex magnetic structures is crucial to understand and develop spintronic materials. Now, a new instrument named ALICE II is available at BESSY II. It allows magnetic X-ray scattering in reciprocal space using a new large area detector. A team at HZB and Technical University Munich has demonstrated the performance of ALICE II by analysing helical and conical magnetic states of an archetypal single crystal skyrmion host. ALICE II is now available for guest users at BESSY II.

The new instrument was conceived and constructed by HZB physicist Dr. Florin Radu and the technical design department at HZB in close cooperation with Prof. Christian Back from the Technical University Munich and his technical support. It is now available for guest users at BESSY II as well.

“ALICE II has an unique capability, namely to allow for magnetic X-ray scattering in reciprocal space using a new large area detector, and this at up to the highest allowed reflected angles”, Radu explains. To demonstrate the performance of the new instrument, the scientists examined a polished sample of Cu2OSeO3.

Read more on the HZB website

Image: The picture reflects the main effect measured with a newly developed instrument ALICE II at BESSY II: A circular polarised soft-X-ray beam scatters off a crystal that exhibits a helical or conical magnetic order. This leads to two scattered beams of different intensity. The difference in intensity of these scattered beams is a measure of the chirality of the equidistant magnetic helices.

Credit: © F. Radu/HZB

A light-induced spin switching device with promising applications in spintronics

A research work led by the University of Valencia (Spain) has reported the fabrication of a novel device that allows the robust electrical detection of a fast and effective light-induced and thermally induced spin transition with an outstanding performance. It represents a tool with promising potential for generating new systems with applications in spintronics and straintronics. Experiments carried out at the BOREAS beamline have been crucial in this study.

The search for more efficient data transport and storage methodologies has helped the development of new research areas, such as molecular spintronics. This novel discipline uses molecular compounds as functional materials in a new generation of devices in which the information tool used is not only the charge (electrons) transport but also the spin. The spin is an intrinsic property of electrons (as mass or electric charge). By adding this new variable of information transport, it is possible to create more efficient electronic devices with a larger capacity for data processing.

There is an increasing demand for discovering new compounds that are functional for spintronics and allow for industrial scalability in its processing. Sublimable spin-crossover (SCO) molecules are compounds of great interest in this matter. These materials can switch between two states called low-spin and high-spin, depending on a variety of external stimuli such as light or temperature. More specifically, compounds based on iron (II) present opposite magnetic properties between both states; paramagnetic in high-spin and diamagnetic in low-spin.

In a novel study published in the journal Advanced Materials, researchers from the Molecular Science Institut (ICMol) from the University of Valencia (UV) in Spain, in collaboration with members from the BOREAS beamline at the ALBA Synchrotron, have developed spin-crossover/graphene hybrid devices by incorporating films of an iron (II) based material, with the properties aforementioned, in its metastable crystallographic phase. Previously thought to be inert regarding spin-crossover, the work developed at the BOREAS beamline has allowed the discovery of interesting thermal and light-induced spin transition capabilities that this crystallographic phase does show when appropriately isolated.

Read more on the ALBA website

Giant Rashba semiconductors show unconventional dynamics with potential applications

Germanium telluride is a strong candidate for use in functional spintronic devices due to its giant Rashba-effect. Now, scientists at HZB have discovered another intriguing phenomenon in GeTe by studying the electronic response to thermal excitation of the samples. To their surprise, the subsequent relaxation proceeded fundamentally different to that of conventional semimetals. By delicately controlling the fine details of the underlying electronic structure, new functionalities of this class of materials could be conceived. 

In recent decades, the complexity and functionality of silicon-based technologies has increased exponentially, commensurate with the ever-growing demand for smaller, more capable devices. However, the silicon age is coming to an end.  With increasing miniaturisation, undesirable quantum effects and thermal losses are becoming an ever-greater obstacle. Further progress requires new materials that harness quantum effects rather than avoid them. Spintronic devices, which use spins of electrons rather than their charge, promise more energy efficient devices with significantly enhanced switching times and with entirely new functionalities.

Spintronic devices are coming

Candidates for spintronic devices are semiconductor materials wherein the spins are coupled with the orbital motion of the electrons. This so-called Rashba effect occurs in a number of non-magnetic semiconductors and semi-metallic compounds and allows, among other things, to manipulate the spins in the material by an electric field.

First study in a non equilibrium state

Germanium telluride hosts one of the largest Rashba effects of all semiconducting systems. Until now, however, germanium telluride has only been studied in thermal equilibrium. Now, for the first time, a team led by HZB physicist Jaime-Sanchez-Barriga has specifically accessed a non-equilibrium state in GeTe samples at BESSY II and investigated in detail how equilibrium is restored in the material on ultrafast (<10-12 seconds) timescales. In the process, the physicists encountered a new and unexpected phenomenon.

First, the sample was excited with an infrared pulse and then measured with high time resolution using angle-resolved photoemission spectroscopy (tr-ARPES). “For the first time, we were able to observe and characterise all phases of excitation, thermalisation and relaxation on ultrashort time scales,” says Sánchez-Barriga. The most important result: “The data show that the thermal equilibrium between the system of electrons and the crystal lattice is restored in a highly unconventional and counterintuitive way”, explains one of the lead authors, Oliver Clark.

Read more on the HZB website

Image: Left: Electronic structure of GeTe taken with 11 eV photons at BESSY-II, showing the band dispersions of bulk (BS) and surface Rashba states (SS1, SS2) in equilibrium. Middle: Zoom-in on the region of the Rashba states measured with fs-laser 6 eV photons. Right: Corresponding out-of-equilibrium dispersions following excitation by the pump pulse.

A magnetic nano-elevator for spintronic devices

Researchers propose and demonstrate for the first time a new concept for the transfer of magnetic data in three dimensions based on geometrical effects for the interconnection of functional spintronic planes. The device is based on a magnetic nanostructure and promotes the spontaneous motion of bits without the need to apply any external stimuli. This work has promising applications in spintronics. Experiments at the CIRCE beamline in ALBA were key to characterize the magnetic structures and confirm their functioning.

Information technologies will be responsible for about 20% of electricity consumption worldwide by 2025, which urgently requires the development of new types of greener nanoelectronic devices. Spintronics, making use of not only the charge of electrons but also of its intrinsic angular momentum (its spin) is an emerging technology that can overcome some of these challenges, thanks to its non-volatility character, full compatibility with CMOS (complementary metal-oxide-semiconductor), low and fast write/reading processes, and high endurance.

However, as nanoelectronic devices move towards denser forms exploiting three dimensions, new mechanisms to efficiently interconnect functional planes become necessary. The shift to 3D devices should enable ultra-highly dense storage and memory devices, but their realization brings huge challenges, from their fabrication to their interconnection or effective heat dissipation.

Read more on the ALBA website

Image: PEEM magnetic nano-elevator

Disorder brings out quantum physical talents

Quantum effects are most noticeable at extremely low temperatures, which limits their usefulness for technical applications. Thin films of MnSb2Te4, however, show new talents due to a small excess of manganese. Apparently, the resulting disorder provides spectacular properties: The material proves to be a topological insulator and is ferromagnetic up to comparatively high temperatures of 50 Kelvin, measurements at BESSY II show.  This makes this class of material suitable for quantum bits, but also for spintronics in general or applications in high-precision metrology.

Quantum effects such as the anomalous quantum Hall effect enable sensors of highest sensitivity, are the basis for spintronic components in future information technologies and also for qubits in quantum computers of the future. However, as a rule, the quantum effects relevant for this only show up clearly enough to make use of them at very low temperatures near absolute zero and in special material systems.

Read more on the HZB website

Image: The Dirac cone is typical for topological insulators and is practically unchanged on all 6 images (ARPES measurements at BESSY II). The blue arrow additionally shows the valence electrons in the volume. The synchrotron light probes both and can thus distinguish the Dirac cone at the surface (electrically conducting) from the three-dimensional volume (insulating).

Credit: © HZB

Scientists streamline process for controlling spin dynamics

Marking a major achievement in the field of spintronics, researchers at the U.S. Department of Energy’s (DOE) Brookhaven National Laboratory and Yale University have demonstrated the ability to control spin dynamics in magnetic materials by altering their thickness. The study, published on the 18th January in Nature Materials, could lead to smaller, more energy-efficient electronic devices.

“Instead of searching for different materials that share the right frequencies, we can now alter the thickness of a single material—iron, in this case—to find a magnetic medium that will enable the transfer of information across a device,” said Brookhaven physicist and principal investigator Valentina Bisogni.

Read more on the BNL website

Image: An artist’s interpretation of measuring the evolution of material properties as a function of thickness using resonant inelastic x-ray scattering.

Germanium telluride’s hidden properties revealed

Germanium Telluride is an interesting candidate material for spintronic devices. In a comprehensive study at BESSY II, a Helmholtz-RSF Joint Research Group has now revealed how the spin texture switches by ferroelectric polarization within individual nanodomains.

Germanium telluride (GeTe) is known as a ferrolectric Rashba semiconductor with a number of interesting properties. The crystals consist of nanodomains, whose ferrolectric polarization can be switched by external electric fields. Because of the so-called Rashba effect, this ferroelectricity can also be used to switch electron spins within each domain. Germanium telluride is therefore an interesting material for spintronic devices, which allow data processing with significantly less energy input.

Russian German Cooperation

Now a team from HZB and the Lomonosov Moscow State University, which has established a Helmholtz-RSF Joint Research Group, has provided comprehensive insights into this material at the nanoscale. The group is headed by physical chemist Dr. Lada Yashina (Lomonosov State University) and HZB physicist Dr. Jaime Sánchez-Barriga. “We have examined the material using a variety of state-of-the-art methods to not only determine its atomic structure, but also the internal correlation between its atomic and electronic structure at the nanoscale,” says Lada Yashina, who produced the high-quality crystalline samples in her laboratory.

Read more on the BESSY II website

Image: The Fermi surface of multidomain GeTe (111) bulk single crystal measured with high-resolution angle-resolved photoemission at BESSY II. © HZB